Diastereoselective reactions of optically active γ-substituted vinyl phosphine oxides

Jonathan Clayden*, Adam Nelson, Stuart Warren

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

20 Citations (Scopus)

Abstract

Dehydration of diphenylphosphinoyl diols (synthesised by asymmetric dihydroxylation of allylic phosphine oxides) gives γ-hydroxy vinyl phosphine oxides. Some diastereoselective reactions of vinyl phosphine oxides with hydrogen, carbon and heteroatomic nucleophiles are discussed.

Original languageEnglish
Pages (from-to)3471-3474
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number19
DOIs
Publication statusPublished - 12 May 1997

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