Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts

Guillaume Dutheuil; Nicklas Selander; Kalman J. Szabo; Varinder K. Aggarwal

doi:10.1055/s-2008-1067144

Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts

Guillaume Dutheuil^*, Nicklas Selander, Kalman J. Szabo, Varinder K. Aggarwal

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

66 Citations (Scopus)

Abstract

A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described.

Original language	English
Pages (from-to)	2293-2297
Number of pages	5
Journal	Synthesis (Germany)
Issue number	14
DOIs	https://doi.org/10.1055/s-2008-1067144
Publication status	Published - 16 Jul 2008

Keywords

allylation
palladium
palladacycles
transition metal
EFFICIENT ROUTE
ENANTIOSELECTIVE PREPARATION
ALLYLBORONIC ACIDS
CARBONYL-COMPOUNDS
AMINO-ACIDS
ALLYLBORATION
SUBSTITUTION
ALDEHYDES
KETONES
ALLYLATION

Access to Document

10.1055/s-2008-1067144

Handle.net

Persistent link

Cite this

@article{b8414d069b2348aabd1120358eb28002,

title = "Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts",

abstract = "A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described.",

keywords = "allylation, palladium, palladacycles, transition metal, EFFICIENT ROUTE, ENANTIOSELECTIVE PREPARATION, ALLYLBORONIC ACIDS, CARBONYL-COMPOUNDS, AMINO-ACIDS, ALLYLBORATION, SUBSTITUTION, ALDEHYDES, KETONES, ALLYLATION",

author = "Guillaume Dutheuil and Nicklas Selander and Szabo, {Kalman J.} and Aggarwal, {Varinder K.}",

year = "2008",

month = jul,

day = "16",

doi = "10.1055/s-2008-1067144",

language = "English",

pages = "2293--2297",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "14",

}

TY - JOUR

T1 - Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts

AU - Dutheuil, Guillaume

AU - Selander, Nicklas

AU - Szabo, Kalman J.

AU - Aggarwal, Varinder K.

PY - 2008/7/16

Y1 - 2008/7/16

N2 - A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described.

AB - A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described.

KW - allylation

KW - palladium

KW - palladacycles

KW - transition metal

KW - EFFICIENT ROUTE

KW - ENANTIOSELECTIVE PREPARATION

KW - ALLYLBORONIC ACIDS

KW - CARBONYL-COMPOUNDS

KW - AMINO-ACIDS

KW - ALLYLBORATION

KW - SUBSTITUTION

KW - ALDEHYDES

KW - KETONES

KW - ALLYLATION

U2 - 10.1055/s-2008-1067144

DO - 10.1055/s-2008-1067144

M3 - Article (Academic Journal)

SN - 0039-7881

SP - 2293

EP - 2297

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 14

ER -

Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts

Abstract

Keywords

Access to Document

Handle.net

Fingerprint

Cite this