Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry

Evan Crawford; Tracy Lohr; Erin M. Leitao; Samantha Kwok; J. Scott McIndoe

doi:10.1039/b913492a

Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry

Evan Crawford, Tracy Lohr, Erin M. Leitao, Samantha Kwok, J. Scott McIndoe

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

17 Citations (Scopus)

Abstract

Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

Original language	English
Pages (from-to)	9110-9112
Number of pages	3
Journal	Dalton Transactions
Issue number	42
DOIs	https://doi.org/10.1039/b913492a
Publication status	Published - 2009

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title = "Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry",

abstract = "Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.",

author = "Evan Crawford and Tracy Lohr and Leitao, {Erin M.} and Samantha Kwok and McIndoe, {J. Scott}",

year = "2009",

doi = "10.1039/b913492a",

language = "English",

pages = "9110--9112",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry

AU - Crawford, Evan

AU - Lohr, Tracy

AU - Leitao, Erin M.

AU - Kwok, Samantha

AU - McIndoe, J. Scott

PY - 2009

Y1 - 2009

N2 - Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

AB - Dimeric tetraalkyldistannoxanes are have been reported to catalyze esterification reactions, but are difficult to investigate in detail due to the lack of suitable spectroscopic handles. Electrospray ionization mass spectrometry (ESI-MS), in conjunction with a tethered charge on a tin atom, reveals that immediate decomposition to mono-tin carboxylate compounds occurs in the presence of carboxylic acid.

U2 - 10.1039/b913492a

DO - 10.1039/b913492a

M3 - Article (Academic Journal)

C2 - 20449182

SN - 1477-9226

SP - 9110

EP - 9112

JO - Dalton Transactions

JF - Dalton Transactions

IS - 42

ER -

Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry

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