Diverse N-heterocyclic ring systems via aza-Heck cyclizations of N-(pentafluorobenzoyloxy)sulfonamides

Ian Hazelden, Xiao-Feng Ma, T Langer, John Bower

Research output: Contribution to journalArticle (Academic Journal)peer-review

32 Citations (Scopus)
372 Downloads (Pure)

Abstract

Aza-Heck cyclizations initiated by oxidative addition of Pd0-catalysts into the N−O bond of N-(pentafluoro-benzoyloxy)sulfonamides are described. These studies, which encompass only the second class of aza-Heck reaction developed to date, provide direct access to diverse N-heterocyclic ring systems.
Original languageEnglish
Pages (from-to)11198-11202
Number of pages6
JournalAngewandte Chemie - International Edition
Volume55
Issue number37
Early online date27 Jul 2016
DOIs
Publication statusPublished - 5 Sep 2016

Keywords

  • aza-Heck reaction
  • cascade reactions
  • N-heterocycles
  • palladium

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