Abstract
I argue that molecules may not have structure in isolation. I support this
by investigating how quantum models identify structure for isolated molecules.
Specifically, I distinguish between two sets of models: those that identify structure
in isolation and those that do not. The former identify structure because they
presuppose structural information about the target system via the Born-
Oppenheimer approximation. However, it is an idealisation to assume structure in
isolation because there is no empirical evidence of this. In fact, whenever structure
is empirically examined it is always partially determined by factors that are absent
in isolation. Together with the growing empirical evidence that isolated molecules
behave in non-classical ways, this shows that the quantum models that do not
identify structure are more faithful representations of isolated molecules.
by investigating how quantum models identify structure for isolated molecules.
Specifically, I distinguish between two sets of models: those that identify structure
in isolation and those that do not. The former identify structure because they
presuppose structural information about the target system via the Born-
Oppenheimer approximation. However, it is an idealisation to assume structure in
isolation because there is no empirical evidence of this. In fact, whenever structure
is empirically examined it is always partially determined by factors that are absent
in isolation. Together with the growing empirical evidence that isolated molecules
behave in non-classical ways, this shows that the quantum models that do not
identify structure are more faithful representations of isolated molecules.
| Original language | English |
|---|---|
| Title of host publication | Philosophical Perspectives on Quantum Chemistry |
| Editors | Olimpia Lombardi, Sebastian Fortin, Juan Camilo Martínez González |
| Publisher | Springer |
| Publication status | Accepted/In press - 30 Nov 2020 |
Publication series
| Name | Synthese Library |
|---|---|
| Publisher | Springer |
Research Groups and Themes
- Centre for Science and Philosophy
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The Problem of Molecular Structure Just Is The Measurement problem
Seifert, V. A. & Franklin, A., 1 Mar 2024, In: British Journal for the Philosophy of Science. 75, 1Research output: Contribution to journal › Article (Academic Journal) › peer-review
Open AccessFile11 Citations (Scopus)135 Downloads (Pure) -
Idealisations to the Rescue
Seifert, V. A., 13 Jan 2021, Royal Society of Chemistry.Research output: Other contribution
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The role of idealisations in describing an isolated molecule
Seifert, V. A., 24 Sept 2019, In: Foundations of Chemistry. 22, p. 15-29 15 p.Research output: Contribution to journal › Article (Academic Journal) › peer-review
Open AccessFile102 Downloads (Pure)
Projects
- 1 Finished
-
MetaScience: The Metaphysical Unity of Science
Tahko, T. (Principal Investigator), Seifert, V. A. (Researcher), Friend, T. T. (Researcher), Kimpton-Nye, S. (Researcher), Bellazzi, F. (Student), Franklin, A. (Other ) & Morgan, W. H. (Researcher)
1/09/18 → 31/08/23
Project: Research
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