Double addition of H-2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres

Nikolaos Tsoureas; Yu-Ying Kuo; Mairi F. Haddow; Gareth R. Owen

doi:10.1039/c0cc02245d

Double addition of H-2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres

Nikolaos Tsoureas, Yu-Ying Kuo, Mairi F. Haddow, Gareth R. Owen

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

94 Citations (Scopus)

Abstract

The addition of H-2 across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

Original language	English
Pages (from-to)	484-486
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	1
DOIs	https://doi.org/10.1039/c0cc02245d
Publication status	Published - Oct 2011

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@article{0d7a99da53544a0aa454a01e75a3f980,

title = "Double addition of H-2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres",

abstract = "The addition of H-2 across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.",

author = "Nikolaos Tsoureas and Yu-Ying Kuo and Haddow, {Mairi F.} and Owen, {Gareth R.}",

year = "2011",

month = oct,

doi = "10.1039/c0cc02245d",

language = "English",

volume = "47",

pages = "484--486",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

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TY - JOUR

T1 - Double addition of H-2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres

AU - Tsoureas, Nikolaos

AU - Kuo, Yu-Ying

AU - Haddow, Mairi F.

AU - Owen, Gareth R.

PY - 2011/10

Y1 - 2011/10

N2 - The addition of H-2 across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

AB - The addition of H-2 across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

U2 - 10.1039/c0cc02245d

DO - 10.1039/c0cc02245d

M3 - Article (Academic Journal)

C2 - 20938529

SN - 1359-7345

VL - 47

SP - 484

EP - 486

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Double addition of H-2 to transition metal-borane complexes: a 'hydride shuttle' process between boron and transition metal centres

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