Effect of Pore Geometry on Ultra-Densified Hydrogen in Microporous Carbons

Mi Tian*, Matthew J Lennox, Alexander J O'Malley, Alexander J Porter, Benjamin Krüner, Svemir Rudić, Timothy J. Mays, Tina Düren, Volker Presser, Lui R Terry, Stephane Rols, Yanan Fang, Zhili Dong, Sebastien Rochat, Valeska P. Ting*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

2 Citations (Scopus)
43 Downloads (Pure)

Abstract

Our investigations into molecular hydrogen (H2) confined in microporous carbons with different pore geometries at 77 K have provided detailed information on effects of pore shape on densification of confined H2 at pressures up to 15 MPa. We selected three materials: a disordered, phenolic resin-based activated carbon, a graphitic carbon with slit-shaped pores (titanium carbide-derived carbon), and single-walled carbon nanotubes, all with comparable pore sizes of < 1 nm. We show via a combination of in situ inelastic neutron scattering studies, high-pressure H2 adsorption measurements, and molecular modelling that both slit-shaped and cylindrical pores with a diameter of ~0.7 nm lead to significant H2 densification compared to bulk hydrogen under the same conditions, with only subtle differences in hydrogen packing (and hence density) due to geometric constraints. While pore geometry may play some part in influencing the diffusion kinetics and packing arrangement of hydrogen molecules in pores, pore size remains the critical factor determining hydrogen storage capacities. This confirmation of the effects of pore geometry and pore size on the confinement of molecules is essential in understanding and guiding the development and scale-up of porous adsorbents that are tailored for maximising H2 storage capacities, in particular for sustainable energy applications.
Original languageEnglish
Pages (from-to)968-979
Number of pages12
JournalCarbon
Volume173
Issue number3
Early online date23 Nov 2020
DOIs
Publication statusPublished - 1 Mar 2021

Bibliographical note

Funding Information:
The authors acknowledge funding from the EPSRC H2FC SUPERGEN Hub (EP/E040071/1, EP/L016354/1, EP/L08365/1, EP/K021109/1, EP/J016454/1) for VPT and MT, an EPSRC Research Fellowship for VPT (EP/R01650X/1), funding from the STFC for beamtime on TOSCA (RB1410602 and RB1610401) and from the ILL (7-05-468) for beamtime on IN4. We also thank Dr Chris Goodway and Dr Mark Kibble (STFC) for user support at ISIS, and Prof. Steve Tennison at CarbonTex for the TE7 carbon beads. VP and BK thank Eduard Arzt (INM) for his continuing support. AJOM acknowledges Roger and Sue Whorrod for the funding of the Whorrod Fellowship. This research made use of the Balena High Performance Computing (HPC) Service at the University of Bath.

Funding Information:
The authors acknowledge funding from the EPSRC H2FC SUPERGEN Hub ( EP/E040071/1 , EP/L016354/1 , EP/L08365/1 , EP/K021109/1 , EP/J016454/1 ) for VPT and MT, an EPSRC Research Fellowship for VPT ( EP/R01650X/1 ), funding from the STFC for beamtime on TOSCA ( RB1410602 and RB1610401 ) and from the ILL (7-05-468) for beamtime on IN4. We also thank Dr Chris Goodway and Dr Mark Kibble (STFC) for user support at ISIS, and Prof. Steve Tennison at CarbonTex for the TE7 carbon beads. VP and BK thank Eduard Arzt (INM) for his continuing support. AJOM acknowledges Roger and Sue Whorrod for the funding of the Whorrod Fellowship. This research made use of the Balena High Performance Computing (HPC) Service at the University of Bath.

Publisher Copyright:
© 2020 The Authors

Keywords

  • microporous carbon
  • hydrogen storage
  • confinement
  • high-pressure adsorption
  • inelastic neutron scattering
  • molecular dynamic simulation

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