Abstract
In situ generated iron‐based Knölker complexes were found to be efficient catalysts
in a fully non‐noble metal Cu–Fe photocatalytic water reduction system. These mononuclear
iron catalysts were able to generate hydrogen up to 15 times faster than previously
reported [Fe3(CO)12]. A reductive quenching mechanism was shown to operate by fluorescence experiments.
| Original language | English |
|---|---|
| Pages (from-to) | 2340-2344 |
| Number of pages | 5 |
| Journal | ChemCatChem |
| Volume | 8 |
| Issue number | 14 |
| Early online date | 17 Jun 2016 |
| DOIs | |
| Publication status | Published - 20 Jul 2016 |
Keywords
- hydrogen
- iron
- photocatalysis
- reduction
- water splitting
Access to Document
- Full-text PDF (accepted author manuscript)
This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Wiley at https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201600186 . Please refer to any applicable terms of use of the publisher.