Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Benjamin M. Partridge; Laetitia Chausset-Boissarie; Matthew Burns; Alexander P. Pulis; Varinder K. Aggarwal

doi:10.1002/anie.201203198

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Benjamin M. Partridge, Laetitia Chausset-Boissarie, Matthew Burns, Alexander P. Pulis, Varinder K. Aggarwal^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

61 Citations (Scopus)

Original language	English
Pages (from-to)	11795-11799
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	47
DOIs	https://doi.org/10.1002/anie.201203198
Publication status	Published - 2012

Research Groups and Themes

BCS and TECS CDTs

Keywords

allenes
boronic esters
cross-coupling
lithiation
propargylic alcohols
ASYMMETRIC-SYNTHESIS
ORGANOBORONIC ESTERS
CONJUGATE BORATION
STEREOSELECTIVE-SYNTHESIS
STEREOCHEMICAL COURSE
SECONDARY ALCOHOLS
ALKYL-HALIDES
ALLENES
NUCLEOPHILES
PHOSPHATES

Access to Document

10.1002/anie.201203198

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Persistent link

GENERAL AND CONVERGENT STRATEGY FOR ASYMMETRIC SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/07 → 1/04/13
Project: Research
NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K. (Principal Investigator)
1/10/05 → 1/10/10
Project: Research

Cite this

@article{397a0d1ce0ab48968aa32cc71de2bdfa,

title = "Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates",

keywords = "allenes, boronic esters, cross-coupling, lithiation, propargylic alcohols, ASYMMETRIC-SYNTHESIS, ORGANOBORONIC ESTERS, CONJUGATE BORATION, STEREOSELECTIVE-SYNTHESIS, STEREOCHEMICAL COURSE, SECONDARY ALCOHOLS, ALKYL-HALIDES, ALLENES, NUCLEOPHILES, PHOSPHATES",

author = "Partridge, {Benjamin M.} and Laetitia Chausset-Boissarie and Matthew Burns and Pulis, {Alexander P.} and Aggarwal, {Varinder K.}",

year = "2012",

doi = "10.1002/anie.201203198",

language = "English",

volume = "51",

pages = "11795--11799",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH Verlag",

number = "47",

}

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates. / Partridge, Benjamin M.; Chausset-Boissarie, Laetitia; Burns, Matthew et al.
In: Angewandte Chemie - International Edition, Vol. 51, No. 47, 2012, p. 11795-11799.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

AU - Partridge, Benjamin M.

AU - Chausset-Boissarie, Laetitia

AU - Burns, Matthew

AU - Pulis, Alexander P.

AU - Aggarwal, Varinder K.

PY - 2012

Y1 - 2012

KW - allenes

KW - boronic esters

KW - cross-coupling

KW - lithiation

KW - propargylic alcohols

KW - ASYMMETRIC-SYNTHESIS

KW - ORGANOBORONIC ESTERS

KW - CONJUGATE BORATION

KW - STEREOSELECTIVE-SYNTHESIS

KW - STEREOCHEMICAL COURSE

KW - SECONDARY ALCOHOLS

KW - ALKYL-HALIDES

KW - ALLENES

KW - NUCLEOPHILES

KW - PHOSPHATES

U2 - 10.1002/anie.201203198

DO - 10.1002/anie.201203198

M3 - Article (Academic Journal)

C2 - 23076714

SN - 1433-7851

VL - 51

SP - 11795

EP - 11799

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 47

ER -

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Research Groups and Themes

Keywords

Access to Document

Handle.net

Projects

GENERAL AND CONVERGENT STRATEGY FOR ASYMMETRIC SYNTHESIS

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

Cite this