Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Benjamin M. Partridge; Laetitia Chausset-Boissarie; Matthew Burns; Alexander P. Pulis; Varinder K. Aggarwal

doi:10.1002/anie.201203198

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Benjamin M. Partridge, Laetitia Chausset-Boissarie, Matthew Burns, Alexander P. Pulis, Varinder K. Aggarwal^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal)

46 Citations (Scopus)

Original language	English
Pages (from-to)	11795-11799
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	47
DOIs	https://doi.org/10.1002/anie.201203198
Publication status	Published - 2012

Structured keywords

BCS and TECS CDTs

Keywords

allenes
boronic esters
cross-coupling
lithiation
propargylic alcohols
ASYMMETRIC-SYNTHESIS
ORGANOBORONIC ESTERS
CONJUGATE BORATION
STEREOSELECTIVE-SYNTHESIS
STEREOCHEMICAL COURSE
SECONDARY ALCOHOLS
ALKYL-HALIDES
ALLENES
NUCLEOPHILES
PHOSPHATES

Access to Document

10.1002/anie.201203198

2 Finished

GENERAL AND CONVERGENT STRATEGY FOR ASYMMETRIC SYNTHESIS
Aggarwal, V. K.
1/10/07 → 1/04/13
Project: Research
NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS
Aggarwal, V. K.
1/10/05 → 1/10/10
Project: Research

Cite this

@article{397a0d1ce0ab48968aa32cc71de2bdfa,

title = "Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates",

keywords = "allenes, boronic esters, cross-coupling, lithiation, propargylic alcohols, ASYMMETRIC-SYNTHESIS, ORGANOBORONIC ESTERS, CONJUGATE BORATION, STEREOSELECTIVE-SYNTHESIS, STEREOCHEMICAL COURSE, SECONDARY ALCOHOLS, ALKYL-HALIDES, ALLENES, NUCLEOPHILES, PHOSPHATES",

author = "Partridge, {Benjamin M.} and Laetitia Chausset-Boissarie and Matthew Burns and Pulis, {Alexander P.} and Aggarwal, {Varinder K.}",

year = "2012",

doi = "10.1002/anie.201203198",

language = "English",

volume = "51",

pages = "11795--11799",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH Verlag",

number = "47",

}

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates. / Partridge, Benjamin M.; Chausset-Boissarie, Laetitia; Burns, Matthew; Pulis, Alexander P.; Aggarwal, Varinder K.

In: Angewandte Chemie - International Edition, Vol. 51, No. 47, 2012, p. 11795-11799.

Research output: Contribution to journal › Article (Academic Journal)

TY - JOUR

T1 - Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

AU - Partridge, Benjamin M.

AU - Chausset-Boissarie, Laetitia

AU - Burns, Matthew

AU - Pulis, Alexander P.

AU - Aggarwal, Varinder K.

PY - 2012

Y1 - 2012

KW - allenes

KW - boronic esters

KW - cross-coupling

KW - lithiation

KW - propargylic alcohols

KW - ASYMMETRIC-SYNTHESIS

KW - ORGANOBORONIC ESTERS

KW - CONJUGATE BORATION

KW - STEREOSELECTIVE-SYNTHESIS

KW - STEREOCHEMICAL COURSE

KW - SECONDARY ALCOHOLS

KW - ALKYL-HALIDES

KW - ALLENES

KW - NUCLEOPHILES

KW - PHOSPHATES

U2 - 10.1002/anie.201203198

DO - 10.1002/anie.201203198

M3 - Article (Academic Journal)

C2 - 23076714

VL - 51

SP - 11795

EP - 11799

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 47

ER -

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Structured keywords

Keywords

Access to Document

GENERAL AND CONVERGENT STRATEGY FOR ASYMMETRIC SYNTHESIS

NEW ASSYMETRIC REACTIONS AND THEIR APPLICATION IN TOTAL SYNTHESIS

Cite this