Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

Benjamin M. Partridge, Laetitia Chausset-Boissarie, Matthew Burns, Alexander P. Pulis, Varinder K. Aggarwal*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)

46 Citations (Scopus)
Original languageEnglish
Pages (from-to)11795-11799
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number47
DOIs
Publication statusPublished - 2012

Structured keywords

  • BCS and TECS CDTs

Keywords

  • allenes
  • boronic esters
  • cross-coupling
  • lithiation
  • propargylic alcohols
  • ASYMMETRIC-SYNTHESIS
  • ORGANOBORONIC ESTERS
  • CONJUGATE BORATION
  • STEREOSELECTIVE-SYNTHESIS
  • STEREOCHEMICAL COURSE
  • SECONDARY ALCOHOLS
  • ALKYL-HALIDES
  • ALLENES
  • NUCLEOPHILES
  • PHOSPHATES

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