Facile synthesis of five strontium niobate metastable crystal compositions via sol-gel ionic liquid synthesis

Omar Gomez Rojas, Sean A Davis, T Nakayama, Simon R Hall*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

Abstract

Ionic liquid syntheses have proven proficiency in the production of metal oxides with diverse functionalities. In this work we use the potential of these solvents to form multicationic solutions to directly synthesize five strontium niobate metastable crystal compositions. Such metastable crystals are characterized via UV-vis spectroscopy, inductively coupled plasma optical emission spectrometer, powder X-Ray diffraction, high-resolution transmission electron microscopy, and crystalline refinements. All metastable crystalline structures are strontium rich with Sr/Nb molar ratios Sr/Nb = 3.54, 3.23, 3.09, 2.66, and 2.22, and are consistent with triclinic with space group P-1 (2).
Original languageEnglish
Number of pages10
JournalCeramics International
Early online date2 Feb 2021
DOIs
Publication statusE-pub ahead of print - 2 Feb 2021

Keywords

  • ceramics
  • metal oxides
  • metastable phases
  • strontium niobates

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