Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: Studies towards dictyol C and α-eudesmol

Kevin I. Booker-Milburn; Brian Cox; Mick Grady; Frank Halley; Shaun Marrison

Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: Studies towards dictyol C and α-eudesmol

Kevin I. Booker-Milburn^*, Brian Cox, Mick Grady, Frank Halley, Shaun Marrison

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

13 Citations (Scopus)

Abstract

The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	4651-4655
Number of pages	5
Journal	Tetrahedron Letters
Volume	41
Issue number	23
Publication status	Published - 12 Jun 2000

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title = "Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: Studies towards dictyol C and α-eudesmol",

abstract = "The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained. (C) 2000 Elsevier Science Ltd.",

author = "Booker-Milburn, {Kevin I.} and Brian Cox and Mick Grady and Frank Halley and Shaun Marrison",

year = "2000",

month = jun,

day = "12",

language = "English",

volume = "41",

pages = "4651--4655",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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TY - JOUR

T1 - Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers

T2 - Studies towards dictyol C and α-eudesmol

AU - Booker-Milburn, Kevin I.

AU - Cox, Brian

AU - Grady, Mick

AU - Halley, Frank

AU - Marrison, Shaun

PY - 2000/6/12

Y1 - 2000/6/12

N2 - The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained. (C) 2000 Elsevier Science Ltd.

AB - The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained. (C) 2000 Elsevier Science Ltd.

UR - http://www.scopus.com/inward/record.url?scp=0034640849&partnerID=8YFLogxK

M3 - Article (Academic Journal)

AN - SCOPUS:0034640849

VL - 41

SP - 4651

EP - 4655

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 23

ER -

Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: Studies towards dictyol C and α-eudesmol

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