Floating nematic phase in colloidal platelet-sphere mixtures

Daniel de Las Heras, Nisha Doshi, Terence Cosgrove, Jonathan Phipps, David I Gittins, Jeroen S van Duijneveldt, Matthias Schmidt

Research output: Contribution to journalArticle (Academic Journal)peer-review

33 Citations (Scopus)


The phase behaviour of colloidal dispersions is interesting for fundamental reasons and for technological applications such as photonic crystals and electronic paper. Sedimentation, which in everyday life is relevant from blood analysis to the shelf life of paint, is a means to determine phase boundaries by observing distinct layers in samples that are in sedimentation-diffusion equilibrium. However, disentangling the effects due to interparticle interactions, which generate the bulk phase diagram, from those due to gravity is a complex task. Here we show that a line in the space of chemical potentials µ(i), where i labels the species, represents a sedimented sample and that each crossing of this sedimentation path with a binodal generates an interface under gravity. Complex phase stacks can result, such as the sandwich of a floating nematic layer between top and bottom isotropic phases that we observed in a mixture of silica spheres and gibbsite platelets.
Original languageEnglish
Article number789
Number of pages5
JournalScientific Reports
Publication statusPublished - 2012


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