Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

VC Gibson; RK O'Reilly; W Reed; DF Wass; AJP White; DJ Williams

doi:10.1039/b204510a

Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

VC Gibson^*, RK O'Reilly, W Reed, DF Wass, AJP White, DJ Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

126 Citations (Scopus)

Abstract

Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.

Original language	English
Pages (from-to)	1850-1851
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b204510a
Publication status	Published - 2002

Keywords

METHYL-METHACRYLATE
CARBON-TETRACHLORIDE
POLYMERIZATION
STYRENE
REACTIVITY
SYSTEM
COBALT

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@article{1adb29e6caec4f01805b6c185befaabc,

title = "Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)",

abstract = "Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.",

keywords = "METHYL-METHACRYLATE, CARBON-TETRACHLORIDE, POLYMERIZATION, STYRENE, REACTIVITY, SYSTEM, COBALT",

author = "VC Gibson and RK O'Reilly and W Reed and DF Wass and AJP White and DJ Williams",

year = "2002",

doi = "10.1039/b204510a",

language = "English",

pages = "1850--1851",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Four-coordinate iron complexes bearing alpha-diimine ligands

T2 - efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

AU - Gibson, VC

AU - O'Reilly, RK

AU - Reed, W

AU - Wass, DF

AU - White, AJP

AU - Williams, DJ

PY - 2002

Y1 - 2002

N2 - Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.

AB - Four-coordinate iron(II) complexes bearing alpha-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive beta-hydrogen chain transfer processes.

KW - METHYL-METHACRYLATE

KW - CARBON-TETRACHLORIDE

KW - POLYMERIZATION

KW - STYRENE

KW - REACTIVITY

KW - SYSTEM

KW - COBALT

U2 - 10.1039/b204510a

DO - 10.1039/b204510a

M3 - Article (Academic Journal)

SN - 1359-7345

SP - 1850

EP - 1851

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

Abstract

Keywords

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