@inbook{5fd76d9c9fb2407a8ea8f4043226ced9,
title = "Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems",
abstract = "The concept of the {"}frustrated{"} Lewis pair (FLP) offers a valuable paradigm for transition metal complexes. This chapter describes recent developments in FLP chemistry where one or both of the Lewis acidic or Lewis basic components are based on a transition metal. At the forefront of these developments have been zirconocene-phosphinoaryloxide complexes; the activation of small molecules, including H-2, CO2, ethers, olefins and alkyl chlorides or fluorides, with such zirconocene (or group 4 metallocene in general) phosphine pairs is described. Nascent catalytic applications for such complexes in dehydrogenation reactions and future possibilities for catalytic reactivity are also highlighted. A wider discussion of how the FLP concept may rationalise previous examples of cooperative reactivity in transition metal complexes, such as the heterolytic cleavage of hydrogen, suggests a strong and useful analogy.",
keywords = "Cooperative effects, Frustrated Lewis pairs, Transition metals, Zirconocenes, ZIRCONOCENE-PHOSPHINOARYLOXIDE COMPLEXES, CHEMICAL HYDROGEN STORAGE, PHOSPHINE-BORANE ADDUCTS, H BOND ACTIVATION, OLEFIN POLYMERIZATION, AMINE-BORANE, STEREOSELECTIVE HYDROGENATION, HETEROLYTIC ACTIVATION, CARBONYL-COMPLEXES, NONCLASSICAL D(0)",
author = "Wass, {Duncan F.} and Chapman, {Andy M.}",
year = "2013",
doi = "10.1007/128_2012_395",
language = "English",
series = "Topics in Current Chemistry",
publisher = "Springer Berlin Heidelberg",
pages = "261--280",
editor = "G Erker and DW Stephan",
booktitle = "FRUSTRATED LEWIS PAIRS II: EXPANDING THE SCOPE",
address = "Germany",
}