Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

Daniel Blair; Siying Zhong; Matthew Hesse; Nagore Zabaleta; Eddie Myers; Varinder Aggarwal

doi:10.1039/C6CC00536E

Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

Daniel Blair, Siying Zhong, Matthew Hesse, Nagore Zabaleta, Eddie Myers, Varinder Aggarwal

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Abstract

Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.

Original language	English
Pages (from-to)	5289-5292
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	30
Early online date	22 Mar 2016
DOIs	https://doi.org/10.1039/C6CC00536E
Publication status	Published - 18 Apr 2016

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BCS and TECS CDTs

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10.1039/C6CC00536E

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This is the final published version of the article (version of record). It first appeared online via Royal Society of Chemistry at DOI: 10.1039/C6CC00536E. Please refer to any applicable terms of use of the publisher.
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FRESCO: Efficient, Flexible Synthesis of Molecules with Tailored Shapes: from Photoswitchable Helices to anti-Cancer Compounds
Aggarwal, V. K.
1/10/15 → 31/03/21
Project: Research
3-month Core Capability for Chemistry Research
Crosby, J.
1/01/13 → 1/04/13
Project: Research
Changing the Synthesis Landscape with Boron at the Helm: from Chiral Organometallics to Assembly Line Synthesis
Aggarwal, V. K.
14/05/12 → 13/01/18
Project: Research

Cite this

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title = "Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions",

abstract = "Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.",

author = "Daniel Blair and Siying Zhong and Matthew Hesse and Nagore Zabaleta and Eddie Myers and Varinder Aggarwal",

year = "2016",

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day = "18",

doi = "10.1039/C6CC00536E",

language = "English",

volume = "52",

pages = " 5289--5292",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

AU - Blair, Daniel

AU - Zhong, Siying

AU - Hesse, Matthew

AU - Zabaleta, Nagore

AU - Myers, Eddie

AU - Aggarwal, Varinder

PY - 2016/4/18

Y1 - 2016/4/18

N2 - Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.

AB - Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.

U2 - 10.1039/C6CC00536E

DO - 10.1039/C6CC00536E

M3 - Article (Academic Journal)

VL - 52

SP - 5289

EP - 5292

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 30

ER -

Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

Abstract

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Projects

FRESCO: Efficient, Flexible Synthesis of Molecules with Tailored Shapes: from Photoswitchable Helices to anti-Cancer Compounds

3-month Core Capability for Chemistry Research

Changing the Synthesis Landscape with Boron at the Helm: from Chiral Organometallics to Assembly Line Synthesis

Cite this