Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

William J. Gee*, Laura K. Cadman, Harina Amer Hamzah, Mary F. Mahon, Paul R. Raithby, Andrew D. Burrows

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

13 Citations (Scopus)

Abstract

Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

Original languageEnglish
Pages (from-to)10839-10842
Number of pages4
JournalInorganic Chemistry
Volume55
Issue number21
Early online date17 Oct 2016
DOIs
Publication statusPublished - 17 Oct 2016

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