Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

William J. Gee; Laura K. Cadman; Harina Amer Hamzah; Mary F. Mahon; Paul R. Raithby; Andrew D. Burrows

doi:10.1021/acs.inorgchem.6b01917

Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

William J. Gee^*, Laura K. Cadman, Harina Amer Hamzah, Mary F. Mahon, Paul R. Raithby, Andrew D. Burrows

^*Corresponding author for this work

Bristol Composites Institute

Research output: Contribution to journal › Article (Academic Journal) › peer-review

19 Citations (Scopus)

Abstract

Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

Original language	English
Pages (from-to)	10839-10842
Number of pages	4
Journal	Inorganic Chemistry
Volume	55
Issue number	21
Early online date	17 Oct 2016
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01917
Publication status	Published - 17 Oct 2016

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title = "Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification",

abstract = "Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.",

author = "Gee, \{William J.\} and Cadman, \{Laura K.\} and \{Amer Hamzah\}, Harina and Mahon, \{Mary F.\} and Raithby, \{Paul R.\} and Burrows, \{Andrew D.\}",

year = "2016",

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day = "17",

doi = "10.1021/acs.inorgchem.6b01917",

language = "English",

volume = "55",

pages = "10839--10842",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

AU - Gee, William J.

AU - Cadman, Laura K.

AU - Amer Hamzah, Harina

AU - Mahon, Mary F.

AU - Raithby, Paul R.

AU - Burrows, Andrew D.

PY - 2016/10/17

Y1 - 2016/10/17

N2 - Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

AB - Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

UR - https://www.scopus.com/pages/publications/84994676979

U2 - 10.1021/acs.inorgchem.6b01917

DO - 10.1021/acs.inorgchem.6b01917

M3 - Article (Academic Journal)

C2 - 27748589

AN - SCOPUS:84994676979

SN - 0020-1669

VL - 55

SP - 10839

EP - 10842

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Furnishing Amine-Functionalized Metal-Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

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