Projects per year
Abstract
Au(I) in combination with AgOTf enables the unprecedented direct and a-stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalysed hydrofunctionalization of the enol ether glycoside. The room temperature
reaction is high yielding and amenable to a wide range of glycal donors and OH nucleophiles.
reaction is high yielding and amenable to a wide range of glycal donors and OH nucleophiles.
Original language | English |
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Pages (from-to) | 14041-14044 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 139 |
Issue number | 40 |
Early online date | 21 Sept 2017 |
DOIs | |
Publication status | Published - 11 Oct 2017 |
Fingerprint
Dive into the research topics of 'Gold(I)-Catalysed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals'. Together they form a unique fingerprint.Projects
- 2 Finished
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3-month Core Capability for Chemistry Research
Crosby, J. (Principal Investigator)
1/01/13 → 1/04/13
Project: Research
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Reworking of Novel tools for Glycoscience
Galan, M. C. (Principal Investigator)
31/03/12 → 30/08/17
Project: Research
Profiles
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Professor M C Galan
- School of Chemistry - Professor of Organic and Biological Chemistry
Person: Academic