Abstract
Allylic amines ( as their protonated ammonium salts) can be epoxidised with high syn diastereoselectivity and regioselectivity at the proximal alkene in substrates with several double bonds using Oxone. The protonated ammonium cation activates the Oxone by hydrogen bonding, thus promoting the oxidation of groups within the vicinity of the complex.
| Original language | English |
|---|---|
| Pages (from-to) | 3448-3450 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 27 |
| DOIs | |
| Publication status | Published - 2005 |
Research Groups and Themes
- Organic & Biological
Keywords
- M-CHLOROPERBENZOIC ACID
- CATALYZED EPOXIDATION
- ALKENYLAMMONIUM SALTS
- ALKENES
- DIMETHYLDIOXIRANE
- MECHANISM
- OLEFINS
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