Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

TJ Clark, CA Russell, I Manners

Research output: Contribution to journalArticle (Academic Journal)peer-review

223 Citations (Scopus)


Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.
Translated title of the contributionHomogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts
Original languageEnglish
Pages (from-to)9582 - 9583
Number of pages2
JournalJournal of the American Chemical Society
Volume128 (30)
Publication statusPublished - Aug 2006

Bibliographical note

Publisher: American Chemical Society


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