Abstract
Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.
Translated title of the contribution | Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts |
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Original language | English |
Pages (from-to) | 9582 - 9583 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 128 (30) |
DOIs | |
Publication status | Published - Aug 2006 |