Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

TJ Clark; CA Russell; I Manners

doi:10.1021/ja062217k

Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

TJ Clark
, CA Russell
, I Manners

Research output: Contribution to journal › Article (Academic Journal) › peer-review

230 Citations (Scopus)

Abstract

Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.

Translated title of the contribution	Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts
Original language	English
Pages (from-to)	9582 - 9583
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128 (30)
DOIs	https://doi.org/10.1021/ja062217k
Publication status	Published - Aug 2006

Bibliographical note

Publisher: American Chemical Society

Research Groups and Themes

Inorganic & Materials

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10.1021/ja062217k

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2006/128/i30/abs/ja062217k.html

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@article{38102d8b3012464cb879cc6869d77815,

title = "Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts",

abstract = "Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.",

author = "TJ Clark and CA Russell and I Manners",

note = "Publisher: American Chemical Society",

year = "2006",

month = aug,

doi = "10.1021/ja062217k",

language = "English",

volume = "128 (30)",

pages = "9582 -- 9583",

journal = "Journal of the American Chemical Society",

issn = "1520-5126",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

AU - Clark, TJ

AU - Russell, CA

AU - Manners, I

N1 - Publisher: American Chemical Society

PY - 2006/8

Y1 - 2006/8

N2 - Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.

AB - Transition metal catalysis represents a relatively unexplored but potentially useful route to form bonds between main group elements. Previous work in the area of amine-borane adduct dehydrocoupling has exclusively employed late transition metal (e.g., Rh) catalysts which were found to predominantly operate via a heterogeneous mechanism. Herein, we present a new, early transition-metal-catalyzed, homogeneous system which exhibits higher activity.

U2 - 10.1021/ja062217k

DO - 10.1021/ja062217k

M3 - Article (Academic Journal)

SN - 1520-5126

VL - 128 (30)

SP - 9582

EP - 9583

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts

Abstract

Bibliographical note

Research Groups and Themes

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