cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]:  a new catalyst for methanol carbonylation

MJ Baker; MF Giles; AG Orpen; MJ Taylor; RJ Watt

doi:10.1039/C39950000197

cis-[RhI(CO)(Ph₂PCH₂P(S)Ph₂)]: a new catalyst for methanol carbonylation

MJ Baker
, MF Giles
, AG Orpen
, MJ Taylor
, RJ Watt

Senior Team

Research output: Contribution to journal › Article (Academic Journal) › peer-review

133 Citations (Scopus)

Abstract

The complex cis-[[graphic omitted]Ph₂)] is eight times more active than the classic Monsanto catalyst [RhI₂(CO)₂]^– for the carbonylation of methanol at 185 °C offering the first promoted system effective under conditions which allow industrially realistic rates; the X-ray crystal structure of the analogue cis-[[graphic omitted]Ph₂)] is reported together with in situ spectroscopic evidence for species in the catalytic cycle.

Translated title of the contribution	cis-[RhI(CO)(Ph₂PCH₂P(S)Ph₂)]: a new catalyst for methanol carbonlylation
Original language	English
Pages (from-to)	197-198
Number of pages	2
Journal	Journal of the Chemical Society: Chemical Communications
Volume	1995
Issue number	2
DOIs	https://doi.org/10.1039/C39950000197
Publication status	Published - 1995

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@article{1167beecdb884dcfa68e230ea34aebd0,

title = "cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]: a new catalyst for methanol carbonylation",

abstract = "The complex cis-[[graphic omitted]Ph2)] is eight times more active than the classic Monsanto catalyst [RhI2(CO)2]– for the carbonylation of methanol at 185 °C offering the first promoted system effective under conditions which allow industrially realistic rates; the X-ray crystal structure of the analogue cis-[[graphic omitted]Ph2)] is reported together with in situ spectroscopic evidence for species in the catalytic cycle.",

author = "MJ Baker and MF Giles and AG Orpen and MJ Taylor and RJ Watt",

year = "1995",

doi = "10.1039/C39950000197",

language = "English",

volume = "1995",

pages = "197--198",

journal = "Journal of the Chemical Society: Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]: a new catalyst for methanol carbonylation

AU - Baker, MJ

AU - Giles, MF

AU - Orpen, AG

AU - Taylor, MJ

AU - Watt, RJ

PY - 1995

Y1 - 1995

N2 - The complex cis-[[graphic omitted]Ph2)] is eight times more active than the classic Monsanto catalyst [RhI2(CO)2]– for the carbonylation of methanol at 185 °C offering the first promoted system effective under conditions which allow industrially realistic rates; the X-ray crystal structure of the analogue cis-[[graphic omitted]Ph2)] is reported together with in situ spectroscopic evidence for species in the catalytic cycle.

AB - The complex cis-[[graphic omitted]Ph2)] is eight times more active than the classic Monsanto catalyst [RhI2(CO)2]– for the carbonylation of methanol at 185 °C offering the first promoted system effective under conditions which allow industrially realistic rates; the X-ray crystal structure of the analogue cis-[[graphic omitted]Ph2)] is reported together with in situ spectroscopic evidence for species in the catalytic cycle.

U2 - 10.1039/C39950000197

DO - 10.1039/C39950000197

M3 - Article (Academic Journal)

SN - 0022-4936

VL - 1995

SP - 197

EP - 198

JO - Journal of the Chemical Society: Chemical Communications

JF - Journal of the Chemical Society: Chemical Communications

IS - 2

ER -

cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]: a new catalyst for methanol carbonylation

Abstract

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cis-[RhI(CO)(Ph₂PCH₂P(S)Ph₂)]: a new catalyst for methanol carbonylation