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Impact of Sb and Na Doping on the Surface Electronic Landscape of Cu2ZnSnS4 Thin Films

Research output: Contribution to journalArticle

Original languageEnglish
Pages (from-to)2977-2982
Number of pages6
JournalACS Energy Letters
Issue number12
Early online date14 Nov 2018
DateAccepted/In press - 14 Nov 2018
DateE-pub ahead of print - 14 Nov 2018
DatePublished (current) - 14 Dec 2018


Open-circuit voltage deficiency is the key limiting factor in Cu2ZnSnS4 (CZTS) thin-film solar cells, which is commonly associated with band tails and deep gap states arising from elemental disorder. The introduction of dopants such as Na and Sb has led to improvement in device performance, yet their effects on the optoelectronic properties of CZTS are yet to be fully elucidated. In this Letter, we unraveled the effect of Sb and Na:Sb co-doping on the surface energy landscape of solution-processed CZTS films employing energy-filtered photoelectron emission microscopy. In the absence of the additives, 150 nm resolution photoemission maps reveal oscillations in the local effective work function as well as areas of low photoemission energy threshold. The introduction of dopants substantially reshapes the photoemission maps, which we rationalize in terms of Cu:Zn and Sn disorder. Finally, we establish unprecedented correlations between the photoemission landscape of thin films and the performance of over 200 devices.

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    Rights statement: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via ACS at DOI: 10.1021/acsenergylett.8b02081. Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 2.22 MB, PDF document


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