Improved Carbon and Nitrogen Isotopic Ratios for CH 3 CN in Titan’s Atmosphere Using ALMA

Titan, Saturn’s largest satellite, maintains an atmosphere composed primarily of nitrogen (N2) and methane (CH4) that leads to complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced 15N abundances compared to Earth and Titan’s dominant nitrogen (N2) reservoir. The 14N/15N isotopic ratio in Titan’s nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan’s large nitrogen abundance. Using high signal-to-noise ratio (>13), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array Band 6 receiver (211–275 GHz), we measure the 14N/15N and 12C/13C isotopic ratios of acetonitrile (CH3CN) in Titan’s stratosphere. Using the NEMESIS, we derived the CH3CN/13CH3CN ratio to be 89.2 ± 7.0 and the CH3CN/CH313CN ratio to be 91.2 ± 6.0, in agreement with the 12C/13C ratio in Titan’s methane and other solar system species. We found the 14N/15N isotopic ratio to be 68.9 ± 4.2, consistent with previously derived values for HCN and HC3N, confirming an enhanced 15N abundance in Titan’s nitriles compared with the bulk atmospheric N2 value of 14N/15N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N2 at high altitudes.