Incipient chemical weathering at bedrock fracture interfaces in a tropical critical zone system, Puerto Rico

Oliver W. Moore*, Heather L. Buss, Anthony Dosseto

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)

3 Citations (Scopus)
38 Downloads (Pure)

Abstract

The processes that control chemical weathering of bedrock in the deep critical zone at a mm-scale are still poorly understood, but may produce 100 s of meters of regolith and substantial fluxes of silicate weathering products and thus may be important for modeling long-term, global CO 2 . Weathering controls are also difficult to ascertain, as laboratory determined dissolution rates tend to be 2–5 orders of magnitude faster than field determined dissolution rates. This study aims to establish (i) the incipient processes that control the chemical weathering of the Bisley bedrock and (ii) why weathering rates calculated for the watershed may differ from laboratory rates (iii) why rates may differ across different scales of measurement. We analyzed mineralogy, elemental chemistry, and porosity in thin sections of rock obtained from drilled boreholes using Scanning Electron Microscopy (SEM) with energy dispersive spectrometry, electron probe microanalysis, and synchrotron-based Micro X-ray Fluorescence (µXRF) and X-ray Absorption Near Edge Structure (XANES). Weathering ages were determined from U-series isotope analysis. Mineral specific dissolution rates were calculated from solid-state mineralogical gradients and weathering ages. Mineralogical and elemental transects across thin sections and SEM images indicate that trace pyrite is the first mineral to dissolve. Micro-XRF mapping at 2 µm resolution revealed sulfate in pore space adjacent to dissolving pyrite, indicating that the incipient reaction is oxidative. The oxidative dissolution of pyrite produces a low pH microenvironment that aids the dissolution of pyroxene and chlorite. The rate-limiting step of weathering advance, and therefore the creation of the critical zone in the Bisley watershed, is pyrite oxidation, despite the low abundance (∼0.5 vol%) of pyrite in the parent rock. The naturally determined dissolution rates presented here either approach, converge with, or in some cases exceed, rates from the literature that have been experimentally determined. The U-series weathering age data on the mm-scale integrates the weathering advance rate over the ∼4.2 ± 0.3 kyrs that the weathering rind took to form. The weathering advance rate calculated at a watershed scale (from stream chemistry data) represents a contemporary weathering advance rate, which compares well with that calculated for the weathering rind, suggesting that the Bisley watershed has been weathering at steady-state for the last ∼4 kyrs.

Original languageEnglish
Pages (from-to)61-87
Number of pages27
JournalGeochimica et Cosmochimica Acta
Volume252
Early online date25 Feb 2019
DOIs
Publication statusPublished - May 2019

Keywords

  • Critical zone
  • Luquillo experimental forest
  • U-series nuclides
  • Weathering rates
  • Weathering rinds

Fingerprint Dive into the research topics of 'Incipient chemical weathering at bedrock fracture interfaces in a tropical critical zone system, Puerto Rico'. Together they form a unique fingerprint.

  • Projects

    LCZO: Luquillo Critical Zone Observatory

    Buss, H. L., Brantley, S. L., Scatena, F. N., Silver, W., Plante, A., Willenbring, J., McDowell, W., Shanley, J., White, A. F., Scholl, M., Johnson, A., Jerolmack, D., Horton, B., Chapela Lara, M. & Moore, O. W.

    1/10/1030/09/13

    Project: Research

    Student Theses

    Chemical weathering of volcanic rocks in the tropics: Using small scale studies to determine the mechanisms, rates and impacts of perturbations

    Author: Moore, O., 14 Nov 2017

    Supervisor: Sherman, D. (Supervisor) & Buss, H. (Supervisor)

    Student thesis: Doctoral ThesisDoctor of Philosophy (PhD)

    File

    Cite this