Insight into the Hydrogen Migration Processes Involved in the Formation of Metal-Borane Complexes: Importance of the Third Arm of the Scorpionate Ligand

Nikos Tsoureas, Alex Hamilton, Mairi F Haddow, Jeremy N. Harvey, A. Guy Orpen, Gareth R. Owen*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

17 Citations (Scopus)

Abstract

The reactions of [Ir(kappa N-3,N,H-Tai)(COD)] and [Ir(kappa N-3,N,H-(Ph)Bai)(COD)] (where Tai = HB(azaindolyl)(3) and (Ph)Bai = Ph(H)B(azaindolyl)(2)) with carbon monoxide result in the formation of Z-type iridium-borane complexes supported by 7-azaindole units. Analysis of the reaction mixtures involving the former complex revealed the formation of a single species in solution, [Ir(eta(1)-C8H13){kappa N-3,N,B-B(azaindolyl)(3)}(CO)(2)], as confirmed by NMR spectroscopy. In the case of the (Ph)Bai complex, a mixture of species was observed. A postulated mechanism for the formation of the new complexes has been provided, supported by computational studies. Computational studies have also focused on the reaction step involving the migration of hydrogen from boron (in the borohydride group) to the iridium center. These investigations have demonstrated a small energy barrier for the hydrogen migration step (Delta G(298) = 10.3 kcal mol(-1)). Additionally, deuterium labeling of the borohydride units in Tai and PhBai confirmed the final position of the former borohydride hydrogen atom in the resulting complexes. The importance of the "third azaindolyl" unit within these transformations and the difference in reactivity between the two ligands are discussed. The selective coordination properties of this family of metallaboratrane complexes have also been investigated and are discussed herein.

Original languageEnglish
Pages (from-to)2840-2856
Number of pages17
JournalOrganometallics
Volume32
Issue number9
DOIs
Publication statusPublished - 13 May 2013

Keywords

  • POLYHYDRIDE CLUSTER COMPLEXES
  • ONLY LEWIS PAIRS
  • TRANSITION-METAL
  • MOLECULAR-STRUCTURES
  • HYDRIDE MIGRATION
  • TRIS(METHIMAZOLYL)BORANE COMPLEXES
  • ISOCYANIDE COMPLEXES
  • CRYSTAL-STRUCTURE
  • BU-T
  • COORDINATION

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