Projects per year
Abstract
Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).
Original language | English |
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Pages (from-to) | 5940-5943 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 33 |
Issue number | 21 |
DOIs | |
Publication status | Published - 10 Nov 2014 |
Structured keywords
- BCS and TECS CDTs
Fingerprint
Dive into the research topics of 'Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex'. Together they form a unique fingerprint.Projects
- 2 Finished
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The Ironworks: a mechanistic foundry for iron-catalysed cross-coupling
1/03/13 → 31/07/17
Project: Research
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Profiles
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Professor Timothy Gallagher
- School of Chemistry - Emeritus Professor
- Elizabeth Blackwell Institute for Health Research
- Synthesis
- Catalysis
- Biological and Archaeological Chemistry
- Bristol Neuroscience
Person: Member, Honorary and Visiting Academic