Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex

Robin B. Bedford; Peter B. Brenner; Emma Carter; Timothy Gallagher; Damien M. Murphy; Dominic R. Pye

doi:10.1021/om500847j

Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex

Robin B. Bedford^*, Peter B. Brenner, Emma Carter, Timothy Gallagher, Damien M. Murphy, Dominic R. Pye

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

114 Citations (Scopus)

Abstract

Activation of B₂pin₂ with ^tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B₂pin₂(^tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)₂] (2).

Original language	English
Pages (from-to)	5940-5943
Number of pages	4
Journal	Organometallics
Volume	33
Issue number	21
DOIs	https://doi.org/10.1021/om500847j
Publication status	Published - 10 Nov 2014

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@article{d61354691649414cb315b9e7f229839f,

title = "Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex",

abstract = "Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).",

author = "Bedford, {Robin B.} and Brenner, {Peter B.} and Emma Carter and Timothy Gallagher and Murphy, {Damien M.} and Pye, {Dominic R.}",

year = "2014",

month = nov,

day = "10",

doi = "10.1021/om500847j",

language = "English",

volume = "33",

pages = "5940--5943",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Iron-catalyzed borylation of alkyl, allyl, and aryl halides

T2 - Isolation of an iron(I) boryl complex

AU - Bedford, Robin B.

AU - Brenner, Peter B.

AU - Carter, Emma

AU - Gallagher, Timothy

AU - Murphy, Damien M.

AU - Pye, Dominic R.

PY - 2014/11/10

Y1 - 2014/11/10

N2 - Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).

AB - Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).

UR - http://www.scopus.com/inward/record.url?scp=84910003839&partnerID=8YFLogxK

U2 - 10.1021/om500847j

DO - 10.1021/om500847j

M3 - Article (Academic Journal)

AN - SCOPUS:84910003839

SN - 0276-7333

VL - 33

SP - 5940

EP - 5943

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex

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The Ironworks: a mechanistic foundry for iron-catalysed cross-coupling

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Emeritus Professor Timothy Gallagher

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Iron-catalyzed borylation of alkyl, allyl, and aryl halides: Isolation of an iron(I) boryl complex

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The Ironworks: a mechanistic foundry for iron-catalysed cross-coupling

3-month Core Capability for Chemistry Research

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Emeritus Professor Timothy Gallagher

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