Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control

André Schäfer; Titel Jurca; Joshua Turner; James R Vance; Kajin Lee; Van An Du; Mairi F Haddow; George R Whittell; Ian Manners

doi:10.1002/anie.201411957

Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control

André Schäfer
, Titel Jurca
, Joshua Turner
, James R Vance
, Kajin Lee
, Van An Du
, Mairi F Haddow
, George R Whittell
, Ian Manners

Research output: Contribution to journal › Article (Academic Journal) › peer-review

74 Citations (Scopus)

Abstract

The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

Original language	English
Pages (from-to)	4836-41
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	16
DOIs	https://doi.org/10.1002/anie.201411957
Publication status	Published - 13 Apr 2015

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10.1002/anie.201411957

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3-month Core Capability for Chemistry Research
Crosby, J. (Principal Investigator)
1/01/13 → 1/04/13
Project: Research
Phosphine-Borane Dehydrocoupling: The Synthesis of Tailored New Materials through Mechanistic Studies of Catalytic Processes
Manners, I. (Principal Investigator)
1/09/12 → 1/12/15
Project: Research

Cite this

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title = "Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control",

abstract = "The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.",

author = "Andr{\'e} Sch{\"a}fer and Titel Jurca and Joshua Turner and Vance, \{James R\} and Kajin Lee and Du, \{Van An\} and Haddow, \{Mairi F\} and Whittell, \{George R\} and Ian Manners",

note = "{\textcopyright} 2015 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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doi = "10.1002/anie.201411957",

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T2 - a convenient route to poly(phosphinoboranes) with molecular-weight control

AU - Schäfer, André

AU - Jurca, Titel

AU - Turner, Joshua

AU - Vance, James R

AU - Lee, Kajin

AU - Du, Van An

AU - Haddow, Mairi F

AU - Whittell, George R

AU - Manners, Ian

PY - 2015/4/13

Y1 - 2015/4/13

N2 - The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

AB - The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

U2 - 10.1002/anie.201411957

DO - 10.1002/anie.201411957

M3 - Article (Academic Journal)

C2 - 25712707

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control

Abstract

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Projects

3-month Core Capability for Chemistry Research

Phosphine-Borane Dehydrocoupling: The Synthesis of Tailored New Materials through Mechanistic Studies of Catalytic Processes

Cite this