Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex

Piotr Jankowski; Claire L. McMullin; Ilya D. Gridnev; A. Guy Orpen; Paul G. Pringle

doi:10.1016/j.tetasy.2010.06.005

Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex

Piotr Jankowski, Claire L. McMullin, Ilya D. Gridnev, A. Guy Orpen, Paul G. Pringle

Research output: Contribution to journal › Article (Academic Journal) › peer-review

15 Citations (Scopus)

Abstract

The enantioselective hydrogenation catalyst [Rh(α-CgPH) ₂(cod)]BF₄, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C₂-and the other with C₁-symmetry. © 2010 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1206-1209
Number of pages	4
Journal	Tetrahedron: Asymmetry
Volume	21
Issue number	9-10
DOIs	https://doi.org/10.1016/j.tetasy.2010.06.005
Publication status	Published - 17 May 2010

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title = "Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex",

abstract = "The enantioselective hydrogenation catalyst [Rh(α-CgPH) 2(cod)]BF4, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C2-and the other with C1-symmetry. {\textcopyright} 2010 Elsevier Ltd. All rights reserved.",

author = "Piotr Jankowski and McMullin, {Claire L.} and Gridnev, {Ilya D.} and Orpen, {A. Guy} and Pringle, {Paul G.}",

year = "2010",

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Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex. / Jankowski, Piotr; McMullin, Claire L.; Gridnev, Ilya D. et al.
In: Tetrahedron: Asymmetry, Vol. 21, No. 9-10, 17.05.2010, p. 1206-1209.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex

AU - Jankowski, Piotr

AU - McMullin, Claire L.

AU - Gridnev, Ilya D.

AU - Orpen, A. Guy

AU - Pringle, Paul G.

PY - 2010/5/17

Y1 - 2010/5/17

N2 - The enantioselective hydrogenation catalyst [Rh(α-CgPH) 2(cod)]BF4, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C2-and the other with C1-symmetry. © 2010 Elsevier Ltd. All rights reserved.

AB - The enantioselective hydrogenation catalyst [Rh(α-CgPH) 2(cod)]BF4, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C2-and the other with C1-symmetry. © 2010 Elsevier Ltd. All rights reserved.

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U2 - 10.1016/j.tetasy.2010.06.005

DO - 10.1016/j.tetasy.2010.06.005

M3 - Article (Academic Journal)

SN - 1362-511X

VL - 21

SP - 1206

EP - 1209

JO - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

IS - 9-10

ER -

Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex

Abstract

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