Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex

Piotr Jankowski, Claire L. McMullin, Ilya D. Gridnev, A. Guy Orpen, Paul G. Pringle

Research output: Contribution to journalArticle (Academic Journal)peer-review

14 Citations (Scopus)

Abstract

The enantioselective hydrogenation catalyst [Rh(α-CgPH) 2(cod)]BF4, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C2-and the other with C1-symmetry. © 2010 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)1206-1209
Number of pages4
JournalTetrahedron: Asymmetry
Volume21
Issue number9-10
DOIs
Publication statusPublished - 17 May 2010

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