Kinetic crystallisation instability in liquids with short-ranged attractions

C. Patrick Royall

Research output: Contribution to journalSpecial issue (Academic Journal)peer-review

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Abstract

Liquids in systems with spherically symmetric interactions are not thermodynamically stable when the range of the attraction is reduced sufficiently. However, these metastable liquids have lifetimes long enough that they are readily observable prior to crystallisation. Here we investigate the fate of liquids when the interaction range is reduced dramatically. Under these conditions, we propose that the liquid becomes kinetically unstable, i.e. its properties are non-stationary on the timescale of structural relaxation. Using molecular dynamics simulations, we find that in the square well model with range 6% of the diameter, the liquid crystallises within the timescale of structural relaxation for state points except those so close to criticality that the lengthscale of density fluctuations couples to the length of the simulation box size for typical system sizes. Even very close to criticality, the liquid exhibits significant structural change on the timescale of relaxation.

Original languageEnglish
Pages (from-to)3076-3084
Number of pages7
JournalMolecular Physics
Volume116
Issue number21-22
Early online date3 Jul 2018
DOIs
Publication statusPublished - 17 Nov 2018

Keywords

  • Crystallisation
  • liquid structure
  • simple liquids

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