Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone

GM Aspinall; M Copsey; JC Jeffery; AP Breakspear; CA Russell; J Slattery

doi:10.1039/b510103d

Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone

GM Aspinall, M Copsey, JC Jeffery, AP Breakspear, CA Russell, J Slattery

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

2 Citations (Scopus)

Abstract

Two rare examples of the crystal structures of large molecular clusters formed from the lithium salts of multianions are reported; the first is the dilithium salt of phenylhydrazine, which forms a tetrameric cage with a core of eight Li and eight N centres; the second is a 32-membered cage which forms from the aggregation of two [B(NNPh)3]6- hexaanions, two [NH-NPh]2- dianions and 16 Li+ cations.

Translated title of the contribution	Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone
Original language	English
Pages (from-to)	1234 - 1238
Number of pages	5
Journal	Dalton Transactions
Volume	9
DOIs	https://doi.org/10.1039/b510103d
Publication status	Published - May 2006

Bibliographical note

Publisher: Royal Society of Chemistry

Research Groups and Themes

Inorganic & Materials

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http://dx.doi.org/10.1039/b510103d

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title = "Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone",

abstract = "Two rare examples of the crystal structures of large molecular clusters formed from the lithium salts of multianions are reported; the first is the dilithium salt of phenylhydrazine, which forms a tetrameric cage with a core of eight Li and eight N centres; the second is a 32-membered cage which forms from the aggregation of two [B(NNPh)3]6- hexaanions, two [NH-NPh]2- dianions and 16 Li+ cations.",

author = "GM Aspinall and M Copsey and JC Jeffery and AP Breakspear and CA Russell and J Slattery",

note = "Publisher: Royal Society of Chemistry",

year = "2006",

month = may,

doi = "10.1039/b510103d",

language = "English",

volume = "9",

pages = "1234 -- 1238",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone

AU - Aspinall, GM

AU - Copsey, M

AU - Jeffery, JC

AU - Breakspear, AP

AU - Russell, CA

AU - Slattery, J

N1 - Publisher: Royal Society of Chemistry

PY - 2006/5

Y1 - 2006/5

N2 - Two rare examples of the crystal structures of large molecular clusters formed from the lithium salts of multianions are reported; the first is the dilithium salt of phenylhydrazine, which forms a tetrameric cage with a core of eight Li and eight N centres; the second is a 32-membered cage which forms from the aggregation of two [B(NNPh)3]6- hexaanions, two [NH-NPh]2- dianions and 16 Li+ cations.

AB - Two rare examples of the crystal structures of large molecular clusters formed from the lithium salts of multianions are reported; the first is the dilithium salt of phenylhydrazine, which forms a tetrameric cage with a core of eight Li and eight N centres; the second is a 32-membered cage which forms from the aggregation of two [B(NNPh)3]6- hexaanions, two [NH-NPh]2- dianions and 16 Li+ cations.

U2 - 10.1039/b510103d

DO - 10.1039/b510103d

M3 - Article (Academic Journal)

SN - 1477-9226

VL - 9

SP - 1234

EP - 1238

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Lithium-nitrogen and lithium-boron-nitrogen cage compounds formed using the phenylhydrazido backbone

Abstract

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