Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides

George R. M. Dowson; Igor V. Shishkov; Duncan F. Wass

doi:10.1021/om100716t

Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides

George R. M. Dowson, Igor V. Shishkov, Duncan F. Wass^*

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

5 Citations (Scopus)

Abstract

Rhodium complexes, promoted by imidazolium or tetraalkylammonium halide salts, catalyze the dehydration of primary alcohols with good conversion and selectivity.

Original language	English
Pages (from-to)	4001-4003
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	18
DOIs	https://doi.org/10.1021/om100716t
Publication status	Published - 27 Sept 2010

Keywords

IONIC LIQUIDS
ACETIC-ACID
OXIDATIVE ADDITION
ETHANOL
IODIDE
CARBONYLATION
ETHYLENE
PHASE
ACETATE
HYDROCARBONS

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@article{dfd8bddaebcb4616b0f2ffe0aeb0e340,

title = "Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides",

abstract = "Rhodium complexes, promoted by imidazolium or tetraalkylammonium halide salts, catalyze the dehydration of primary alcohols with good conversion and selectivity.",

keywords = "IONIC LIQUIDS, ACETIC-ACID, OXIDATIVE ADDITION, ETHANOL, IODIDE, CARBONYLATION, ETHYLENE, PHASE, ACETATE, HYDROCARBONS",

author = "Dowson, {George R. M.} and Shishkov, {Igor V.} and Wass, {Duncan F.}",

year = "2010",

month = sep,

day = "27",

doi = "10.1021/om100716t",

language = "English",

volume = "29",

pages = "4001--4003",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides

AU - Dowson, George R. M.

AU - Shishkov, Igor V.

AU - Wass, Duncan F.

PY - 2010/9/27

Y1 - 2010/9/27

N2 - Rhodium complexes, promoted by imidazolium or tetraalkylammonium halide salts, catalyze the dehydration of primary alcohols with good conversion and selectivity.

AB - Rhodium complexes, promoted by imidazolium or tetraalkylammonium halide salts, catalyze the dehydration of primary alcohols with good conversion and selectivity.

KW - IONIC LIQUIDS

KW - ACETIC-ACID

KW - OXIDATIVE ADDITION

KW - ETHANOL

KW - IODIDE

KW - CARBONYLATION

KW - ETHYLENE

KW - PHASE

KW - ACETATE

KW - HYDROCARBONS

U2 - 10.1021/om100716t

DO - 10.1021/om100716t

M3 - Article (Academic Journal)

SN - 0276-7333

VL - 29

SP - 4001

EP - 4003

JO - Organometallics

JF - Organometallics

IS - 18

ER -

Low-Temperature Rhodium-Catalyzed Dehydration of Primary Alcohols Promoted by Tetralkylammonium and Imidazolium Halides

Abstract

Keywords

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