Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem; Valeska P Ting; Ulrich Hintermair; Mi Tian; Richard Telford; Saaiba Halim; Harriott Nowell; Małgorzata Hołyńska; Simon J Teat; Ian J Scowen; Sanjit Nayak

doi:10.1039/c6cc03787a

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

Ayesha Naeem, Valeska P Ting, Ulrich Hintermair, Mi Tian, Richard Telford, Saaiba Halim, Harriott Nowell, Małgorzata Hołyńska, Simon J Teat, Ian J Scowen, Sanjit Nayak

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Abstract

Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO₂ over N₂ with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m² g⁻¹.

Original language	English
Pages (from-to)	7826-7829
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	50
Early online date	17 May 2016
DOIs	https://doi.org/10.1039/c6cc03787a
Publication status	Published - 25 Jun 2016

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This is the final published version of the article (version of record). It first appeared online via RSC at http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC03787A#!divAbstract. Please refer to any applicable terms of use of the publisher.
Final published version, 5.86 MBLicence: CC BY

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Professor Valeska Ting
- v.tingbristol.acuk
- Department of Mechanical Engineering - Professor of Smart Nanomaterials
- Bristol Composites Institute (ACCIS)
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title = "Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity",

abstract = "Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.",

author = "Ayesha Naeem and Ting, {Valeska P} and Ulrich Hintermair and Mi Tian and Richard Telford and Saaiba Halim and Harriott Nowell and Ma{\l}gorzata Ho{\l}y{\'n}ska and Teat, {Simon J} and Scowen, {Ian J} and Sanjit Nayak",

year = "2016",

month = jun,

day = "25",

doi = "10.1039/c6cc03787a",

language = "English",

volume = "52",

pages = "7826--7829",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

AU - Naeem, Ayesha

AU - Ting, Valeska P

AU - Hintermair, Ulrich

AU - Tian, Mi

AU - Telford, Richard

AU - Halim, Saaiba

AU - Nowell, Harriott

AU - Hołyńska, Małgorzata

AU - Teat, Simon J

AU - Scowen, Ian J

AU - Nayak, Sanjit

PY - 2016/6/25

Y1 - 2016/6/25

N2 - Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.

AB - Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.

U2 - 10.1039/c6cc03787a

DO - 10.1039/c6cc03787a

M3 - Article (Academic Journal)

C2 - 27242066

VL - 52

SP - 7826

EP - 7829

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 50

ER -

Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity

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