Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.
|Number of pages||4|
|Early online date||17 May 2016|
|Publication status||Published - 25 Jun 2016|
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Professor Valeska Ting
- Department of Mechanical Engineering - Professor of Smart Nanomaterials
- Bristol Composites Institute (ACCIS)