Molecular insights into sodium dodecyl sulphate mediated control of size for silver nanoparticles

V. Shah, B. Bharatiya*, M. K. Mishra, D. Ray, D. O. Shah

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

11 Citations (Scopus)


A specific condition directing the formation of silver nanoparticles (AgNPs) with narrow size-distribution in aqueous sodium dodecyl sulphate (SDS) solutions, using trisodium citrate (TSC) is investigated. The peculiar control in distribution of size for AgNPs in presence of 35 mM (~1 wt%) aqueous SDS solution as stabilizing agent is evident. Water penetration through packed PTFE powder and dynamic surface tension measurements demonstrate formation of stable aggregates at the given condition and accordingly reduced numbers of free SDS monomers diffusing to the growing AgNP interface. The smaller size of AgNPs was also confirmed by TEM images, which illustrates mixed morphologies for the nanoparticles in an aggregated state. The NMR experiments reveal strong hydrophobic interactions between the alkyl chains of SDS molecules adsorbed on AgNPs. These results also indicate that TSC is molecularly distributed in bulk phase without binding to the SDS micellar aggregates. A plausible molecular mechanism is proposed based on diffusion of Ag+ ions to the growing AgNP surface along with SDS monomers and submicellar aggregates, subsequently forming bigger size AgNPs. The narrow distribution of size for AgNP in presence of 35 mM SDS is arguably driven by the capping of stable SDS micelles or monomers around growing nuclei and restricted number of SDS monomers and submicellar aggregates responsible for supply of Ag+ at the growing AgNP nuclei.

Original languageEnglish
Pages (from-to)222-230
Number of pages9
JournalJournal of Molecular Liquids
Early online date10 Oct 2018
Publication statusPublished - 1 Jan 2019


  • Micellar stability
  • Monomers
  • Nucleation
  • Polydispersity
  • Wettability


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