Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly

Daliao Tao; Chun Feng; Yinan Cui; Xian Yang; Ian Manners; Mitchell Winnik; Xiaoyu Huang

doi:10.1021/jacs.7b02208

Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly

Daliao Tao, Chun Feng, Yinan Cui, Xian Yang, Ian Manners, Mitchell Winnik, Xiaoyu Huang

Research output: Contribution to journal › Article (Academic Journal) › peer-review

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Abstract

We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylene vinylene) (OPV)-core and a poly(N-isopropyl acrylamide) (PNIPAM) corona via two different crystallization-driven selfassembly
(CDSA) strategies. The average length Ln of these micelles a can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock co-micelles with an OPV-core.

Original language	English
Pages (from-to)	7136-7139
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	21
Early online date	17 May 2017
DOIs	https://doi.org/10.1021/jacs.7b02208
Publication status	Published - 31 May 2017

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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via ACS at http://pubs.acs.org/doi/abs/10.1021/jacs.7b02208. Please refer to any applicable terms of use of the publisher.
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This is the author accepted manuscript (AAM). The final published version (version of record) is available online via ACS at http://pubs.acs.org/doi/abs/10.1021/jacs.7b02208. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 2.86 MBLicence: CC BY-NC

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@article{287f75a2dcf0417aa227e0a2884552bd,

title = "Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly",

abstract = "We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylene vinylene) (OPV)-core and a poly(N-isopropyl acrylamide) (PNIPAM) corona via two different crystallization-driven selfassembly(CDSA) strategies. The average length Ln of these micelles a can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock co-micelles with an OPV-core. ",

author = "Daliao Tao and Chun Feng and Yinan Cui and Xian Yang and Ian Manners and Mitchell Winnik and Xiaoyu Huang",

year = "2017",

month = may,

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doi = "10.1021/jacs.7b02208",

language = "English",

volume = "139",

pages = "7136--7139",

journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly. / Tao, Daliao; Feng, Chun; Cui, Yinan et al.
In: Journal of the American Chemical Society, Vol. 139, No. 21, 31.05.2017, p. 7136-7139.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly

AU - Tao, Daliao

AU - Feng, Chun

AU - Cui, Yinan

AU - Yang, Xian

AU - Manners, Ian

AU - Winnik, Mitchell

AU - Huang, Xiaoyu

PY - 2017/5/31

Y1 - 2017/5/31

N2 - We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylene vinylene) (OPV)-core and a poly(N-isopropyl acrylamide) (PNIPAM) corona via two different crystallization-driven selfassembly(CDSA) strategies. The average length Ln of these micelles a can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock co-micelles with an OPV-core.

AB - We report the preparation of a series of fiber-like micelles of narrow length distribution with an oligo(p-phenylene vinylene) (OPV)-core and a poly(N-isopropyl acrylamide) (PNIPAM) corona via two different crystallization-driven selfassembly(CDSA) strategies. The average length Ln of these micelles a can be varied up to 870 nm by varying the temperature in self-seeding experiments. In addition, seeded growth was employed not only to prepare uniform micelles of controlled length, but also to form fiber-like A-B-A triblock co-micelles with an OPV-core.

U2 - 10.1021/jacs.7b02208

DO - 10.1021/jacs.7b02208

M3 - Article (Academic Journal)

C2 - 28513145

SN - 0002-7863

VL - 139

SP - 7136

EP - 7139

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 21

ER -

Monodisperse Fiber-like Micelles of Controlled Length and Composition with an Oligo(p-phenylenevinylene) Core via “Living” Crystallization-Driven Self-Assembly

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