Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.

Matthew Bain; Christopher S. Hansen; Michael N.R. Ashfold

doi:10.1063/1.5048838

Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.

Matthew Bain, Christopher S. Hansen, Michael N.R. Ashfold

Research output: Contribution to journal › Article (Academic Journal) › peer-review

10 Citations (Scopus)

284 Downloads (Pure)

Abstract

This study of the photodissociation of dimethyl sulfide at λ = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging.

Original language	English
Article number	081103
Number of pages	5
Journal	Journal of Chemical Physics
Volume	149
Issue number	8
DOIs	https://doi.org/10.1063/1.5048838
Publication status	Published - 30 Aug 2018

Access to Document

10.1063/1.5048838Licence: Unspecified

Full-text PDF (accepted author manuscript)
This is the accepted author manuscript (AAM). The final published version (version of record) is available online via AIP at https://doi.org/10.1063/1.5048838 . Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 2.88 MBLicence: Unspecified

Handle.net

Persistent link

Cite this

@article{1b97c852125d4645b045b538e3275837,

title = "Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.",

abstract = "This study of the photodissociation of dimethyl sulfide at λ = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging.",

author = "Matthew Bain and Hansen, {Christopher S.} and Ashfold, {Michael N.R.}",

year = "2018",

month = aug,

day = "30",

doi = "10.1063/1.5048838",

language = "English",

volume = "149",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics (AIP)",

number = "8",

}

TY - JOUR

T1 - Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.

AU - Bain, Matthew

AU - Hansen, Christopher S.

AU - Ashfold, Michael N.R.

PY - 2018/8/30

Y1 - 2018/8/30

N2 - This study of the photodissociation of dimethyl sulfide at λ = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging.

AB - This study of the photodissociation of dimethyl sulfide at λ = 227.5 nm demonstrates the opportunities (and some of the challenges) of product detection using vacuum ultraviolet photoionization combined with recently developed multi-mass imaging methods. The capability of imaging different charged products simultaneously allows determination of the primary fragmentation dynamics through, for example, product fragment momentum and angular distribution matching and reveals potential complications from dissociative ionization, product alignment-dependent photoionization probabilities, and the effects of space charging.

UR - http://www.scopus.com/inward/record.url?scp=85052724548&partnerID=8YFLogxK

U2 - 10.1063/1.5048838

DO - 10.1063/1.5048838

M3 - Article (Academic Journal)

C2 - 30193497

AN - SCOPUS:85052724548

SN - 0021-9606

VL - 149

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

M1 - 081103

ER -

Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.

Abstract

Access to Document

Handle.net

Other files and links

Fingerprint

Chemical Applications of Velocity & Spatial Imaging

Multi-mass velocity map imaging study of the ultraviolet photodissociation of dimethyl sulfide using single photon ionization and a PImMS2 sensor

Cite this

Multi-mass velocity map imaging study of the ultraviolet photodissociaton of dimethyl sulfide using single photon ionization and a PImMS2 sensor.

Abstract

Access to Document

Handle.net

Other files and links

Fingerprint

Projects

Chemical Applications of Velocity & Spatial Imaging

Datasets

Multi-mass velocity map imaging study of the ultraviolet photodissociation of dimethyl sulfide using single photon ionization and a PImMS2 sensor

Cite this