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N-H carbazoles can be produced from 2-chloroanilines and aryl bromides via consecutive catalytic amination and C-H activation. In many instances, this can be done in a tandem manner in one pot. The methodologies developed can be used in the synthesis of a range of carbazoles, including the natural products Clausine P and glycozolidine and a precursor in the synthesis of Clausines H, K, O, and 7-methoxy-O-methylmukonal, and can be extended to the synthesis of indoles.
|Translated title of the contribution||N-H carbazole synthesis from 2-chloroanilines via consecutive amination and C-H activation|
|Pages (from-to)||9403 - 9410|
|Number of pages||8|
|Journal||Journal of Organic Chemistry|
|Publication status||Published - Dec 2006|
Bibliographical notePublisher: American Chemical Society
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