Near-infrared luminescence from platinum(II) diimine compounds

CJ Adams; N Fey; JA Weinstein

doi:10.1021/ic060399d

Near-infrared luminescence from platinum(II) diimine compounds

CJ Adams, N Fey, JA Weinstein

Research output: Contribution to journal › Article (Academic Journal) › peer-review

54 Citations (Scopus)

Abstract

Square-planar Pt(II) complexes of the bis(mesitylimino)acenaphthene (mesBIAN) ligand are emissive from a MMLL'CT excited state in a dichloromethane solution at room temperature. Investigation of the nature of the frontier orbitals in these near-IR emitters by a combination of emission spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory calculations suggests that emission is enabled by the presence of low-lying ligand π* orbitals on the mesBIAN.

Translated title of the contribution	Near-infrared luminescence from platinum(II) diimine compounds
Original language	English
Pages (from-to)	6105 - 6107
Number of pages	3
Journal	Inorganic Chemistry
Volume	45 (16)
DOIs	https://doi.org/10.1021/ic060399d
Publication status	Published - Aug 2006

Bibliographical note

Publisher: American Chemical Society
Other identifier: IDS Number 068S1

Access to Document

10.1021/ic060399d

http://pubs.acs.org/cgi-bin/abstract.cgi/inocaj/2006/45/i16/abs/ic060399d.html

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title = "Near-infrared luminescence from platinum(II) diimine compounds",

abstract = "Square-planar Pt(II) complexes of the bis(mesitylimino)acenaphthene (mesBIAN) ligand are emissive from a MMLL'CT excited state in a dichloromethane solution at room temperature. Investigation of the nature of the frontier orbitals in these near-IR emitters by a combination of emission spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory calculations suggests that emission is enabled by the presence of low-lying ligand π* orbitals on the mesBIAN.",

author = "CJ Adams and N Fey and JA Weinstein",

note = "Publisher: American Chemical Society Other identifier: IDS Number 068S1",

year = "2006",

month = aug,

doi = "10.1021/ic060399d",

language = "English",

volume = "45 (16)",

pages = "6105 -- 6107",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Near-infrared luminescence from platinum(II) diimine compounds

AU - Adams, CJ

AU - Fey, N

AU - Weinstein, JA

N1 - Publisher: American Chemical Society Other identifier: IDS Number 068S1

PY - 2006/8

Y1 - 2006/8

N2 - Square-planar Pt(II) complexes of the bis(mesitylimino)acenaphthene (mesBIAN) ligand are emissive from a MMLL'CT excited state in a dichloromethane solution at room temperature. Investigation of the nature of the frontier orbitals in these near-IR emitters by a combination of emission spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory calculations suggests that emission is enabled by the presence of low-lying ligand π* orbitals on the mesBIAN.

AB - Square-planar Pt(II) complexes of the bis(mesitylimino)acenaphthene (mesBIAN) ligand are emissive from a MMLL'CT excited state in a dichloromethane solution at room temperature. Investigation of the nature of the frontier orbitals in these near-IR emitters by a combination of emission spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory calculations suggests that emission is enabled by the presence of low-lying ligand π* orbitals on the mesBIAN.

U2 - 10.1021/ic060399d

DO - 10.1021/ic060399d

M3 - Article (Academic Journal)

VL - 45 (16)

SP - 6105

EP - 6107

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -