Near-infrared luminescence from platinum(II) diimine compounds

CJ Adams, N Fey, JA Weinstein

Research output: Contribution to journalArticle (Academic Journal)peer-review

54 Citations (Scopus)

Abstract

Square-planar Pt(II) complexes of the bis(mesitylimino)acenaphthene (mesBIAN) ligand are emissive from a MMLL'CT excited state in a dichloromethane solution at room temperature. Investigation of the nature of the frontier orbitals in these near-IR emitters by a combination of emission spectroscopy, electron paramagnetic resonance spectroscopy, and density functional theory calculations suggests that emission is enabled by the presence of low-lying ligand π* orbitals on the mesBIAN.
Translated title of the contributionNear-infrared luminescence from platinum(II) diimine compounds
Original languageEnglish
Pages (from-to)6105 - 6107
Number of pages3
JournalInorganic Chemistry
Volume45 (16)
DOIs
Publication statusPublished - Aug 2006

Bibliographical note

Publisher: American Chemical Society
Other identifier: IDS Number 068S1

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