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Abstract
Under carbonylative conditions, neutral Rh(I)-systems modified with weak donor ligands (AsPh3 or 1,4-oxathiane) undergo N-Cbz, N-benzoyl or N-Ts directed insertion into the proximal C-C bond of aminomethylcyclopropanes to generate rhodacyclopentanone intermediates. These are trapped by N-tethered alkenes to provide complex perhydroisoindoles.
Original language | English |
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Pages (from-to) | 13501-13504 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 138 |
Issue number | 41 |
Early online date | 6 Oct 2016 |
DOIs | |
Publication status | Published - 19 Oct 2016 |
Structured keywords
- BCS and TECS CDTs
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Dive into the research topics of 'New Initiation Modes for Directed Carbonylative C-C Bond Activation: Rhodium-Catalyzed (3+1+2) Cycloadditions of Aminomethylcyclopropanes'. Together they form a unique fingerprint.Projects
- 2 Finished