New Three-Dimensional Metal-Organic Framework with Heterometallic [Fe-Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies

Sanjit Nayak; Klaus  Harms; Stefanie  Dehnen

doi:10.1021/ic1019636

New Three-Dimensional Metal-Organic Framework with Heterometallic [Fe-Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies

Sanjit Nayak, Klaus Harms, Stefanie Dehnen^*

^*Corresponding author for this work

School of Civil, Aerospace and Design Engineering

Research output: Contribution to journal › Article (Academic Journal) › peer-review

55 Citations (Scopus)

Abstract

A new three-dimensional metal−organic framework (MOF) containing FeII and AgI ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.

Original language	English
Pages (from-to)	2714–2716
Number of pages	3
Journal	Inorganic Chemistry
Volume	50
Issue number	7
Early online date	1 Mar 2011
DOIs	https://doi.org/10.1021/ic1019636
Publication status	Published - 4 Apr 2011

Access to Document

10.1021/ic1019636

Handle.net

Persistent link

Cite this

@article{fc41008f535944b3a6531a2c10da0556,

title = "New Three-Dimensional Metal-Organic Framework with Heterometallic [Fe-Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies",

abstract = "A new three-dimensional metal−organic framework (MOF) containing FeII and AgI ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 {\AA}, with 23.8\% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis. ",

author = "Sanjit Nayak and Klaus Harms and Stefanie Dehnen",

year = "2011",

month = apr,

day = "4",

doi = "10.1021/ic1019636",

language = "English",

volume = "50",

pages = "2714–2716",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - New Three-Dimensional Metal-Organic Framework with Heterometallic [Fe-Ag] Building Units

T2 - Synthesis, Crystal Structure, and Functional Studies

AU - Nayak, Sanjit

AU - Harms, Klaus

AU - Dehnen, Stefanie

PY - 2011/4/4

Y1 - 2011/4/4

N2 - A new three-dimensional metal−organic framework (MOF) containing FeII and AgI ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.

AB - A new three-dimensional metal−organic framework (MOF) containing FeII and AgI ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.

U2 - 10.1021/ic1019636

DO - 10.1021/ic1019636

M3 - Article (Academic Journal)

SN - 0020-1669

VL - 50

SP - 2714

EP - 2716

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

New Three-Dimensional Metal-Organic Framework with Heterometallic [Fe-Ag] Building Units: Synthesis, Crystal Structure, and Functional Studies

Abstract

Access to Document

Handle.net

Fingerprint

Cite this