TY - JOUR
T1 - Non-biaryl atropisomers
T2 - New classes of chiral reagents, auxiliaries, and ligands?
AU - Clayden, J.
PY - 1997/5/16
Y1 - 1997/5/16
N2 - Commonly observed, but rarely exploited, is the restricted rotation about C-C single bonds inherent in certain non-biaryl compounds. Recent examples of stereoselective reactions directed by atropisomeric amides (such as that shown below) point the way to a future for these compounds as tools for asymmetric synthesis.
AB - Commonly observed, but rarely exploited, is the restricted rotation about C-C single bonds inherent in certain non-biaryl compounds. Recent examples of stereoselective reactions directed by atropisomeric amides (such as that shown below) point the way to a future for these compounds as tools for asymmetric synthesis.
KW - amides
KW - asymmetric syntheses
KW - atropisomerism
KW - chirality
KW - isomerism
UR - http://www.scopus.com/inward/record.url?scp=0030917481&partnerID=8YFLogxK
U2 - 10.1002/anie.199709491
DO - 10.1002/anie.199709491
M3 - Article (Academic Journal)
AN - SCOPUS:0030917481
VL - 36
SP - 949
EP - 951
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 9
ER -