Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Christopher A. Russell; John Bower; Edward Emmett; Matt Harper

doi:10.1021/jacs.7b06668

Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Christopher A. Russell, John Bower, Edward Emmett, Matt Harper

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Abstract

Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.

Original language	English
Pages (from-to)	12386-12389
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	36
Early online date	5 Sept 2017
DOIs	https://doi.org/10.1021/jacs.7b06668
Publication status	Published - 13 Sept 2017

Structured keywords

BCS and TECS CDTs

Keywords

gold; catalysis;
commodity chemicals

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A 13C NMR Coldprobe to Underpin Chemistry Research.
Butts, C. P.
28/02/14 → 29/11/17
Project: Research
3-month Core Capability for Chemistry Research
Crosby, J.
1/01/13 → 1/04/13
Project: Research

Dr Chris A Russell
- Chris.Russellbristol.acuk
- School of Chemistry - Reader
Person: Academic

Cite this

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title = "Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation",

abstract = "Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical. ",

keywords = "gold; catalysis; , commodity chemicals",

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journal = "Journal of the American Chemical Society",

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AU - Emmett, Edward

AU - Harper, Matt

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Y1 - 2017/9/13

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AB - Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.

KW - gold; catalysis;

KW - commodity chemicals

U2 - 10.1021/jacs.7b06668

DO - 10.1021/jacs.7b06668

M3 - Article (Academic Journal)

C2 - 28829593

SN - 0002-7863

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 36

ER -

Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Abstract

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A 13C NMR Coldprobe to Underpin Chemistry Research.

3-month Core Capability for Chemistry Research

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Dr Chris A Russell

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