Palladium-Catalyzed Insertion of CO2 into Vinylaziridines: New Route to 5-Vinyloxazolidinones

Francesco Fontana, Chia-Chun Chen, Varinder K. Aggarwal*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

93 Citations (Scopus)

Abstract

2-Vinylaziridines undergo a mild Pd-catalyzed ring-opening cyclization reaction with an ambient atmosphere of carbon dioxide to give 5-vinyloxazolidinones. The process is high yielding as well as regio- and stereoselective.

Original languageEnglish
Pages (from-to)3454-3457
Number of pages4
JournalOrganic Letters
Volume13
Issue number13
DOIs
Publication statusPublished - 1 Jul 2011

Keywords

  • IN-VITRO ACTIVITY
  • CARBON-DIOXIDE
  • DECARBOXYLATIVE CARBONYLATION
  • OXAZOLIDINONE
  • 3,6-DIHYDRO-1H-PYRIDIN-2-ONES
  • REGIOSELECTIVITY
  • ISOCYANATES
  • AZIRIDINES
  • 2-VINYLAZIRIDINES
  • TRANSFORMATION

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