Paramagnetic Titanium(III) and Zirconium(III) Metallocene Complexes as Precatalysts for the Dehydrocoupling/Dehydrogenation of Amine-Boranes

Holger Helten, Barnali Dutta, James R. Vance, Matthew E. Sloan, Mairi F. Haddow, Stephen Sproules, David Collison, George R. Whittell, Guy C. Lloyd-Jones, Ian Manners*

*Corresponding author for this work

Research output: Contribution to journalArticle (Academic Journal)peer-review

62 Citations (Scopus)
Original languageEnglish
Pages (from-to)437-440
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number1
DOIs
Publication statusPublished - 2013

Keywords

  • amine-boranes
  • dehydrogenation
  • metallocenes
  • phosphine-boranes
  • transition metals
  • MOLECULAR-WEIGHT POLYAMINOBORANES
  • FREE HYDROGEN-TRANSFER
  • AMMONIA-BORANE
  • TRANSITION-METAL
  • PHOSPHINE-BORANE
  • CATALYTIC DEHYDROCOUPLING/DEHYDROGENATION
  • AMIDOBORANE COMPLEXES
  • DEHYDROGENATION
  • ADDUCTS
  • CENTERS

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