Pd(II)‐Catalyzed C-H Activation of Styrylindoles:: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

Rakesh K Saunthwal; Monika Patel; Sonu Kumar; Abhinandan K. Danodia; Akhilesh K. Verma

doi:10.1002/chem.201503657

Pd(II)‐Catalyzed C-H Activation of Styrylindoles: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

Rakesh K Saunthwal
, Monika Patel
, Sonu Kumar
, Abhinandan K. Danodia
, Akhilesh K. Verma

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

56 Citations (Scopus)

Abstract

A novel PdII‐catalyzed approach for the direct synthesis of highly functionalized carbazoles from unprotected styrylindoles has been developed. The reaction features a variety of olefin substrates, which are readily switchable by subtle tuning of the reaction conditions. Investigations of the mechanism suggest that the C-H activation proceeds via enamine formation.

Original language	English
Pages (from-to)	18601-18605
Number of pages	5
Journal	Chemistry - A European Journal
Volume	21
Issue number	51
DOIs	https://doi.org/10.1002/chem.201503657
Publication status	E-pub ahead of print - 6 Oct 2015

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title = "Pd(II)‐Catalyzed C-H Activation of Styrylindoles:: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles",

abstract = "A novel PdII‐catalyzed approach for the direct synthesis of highly functionalized carbazoles from unprotected styrylindoles has been developed. The reaction features a variety of olefin substrates, which are readily switchable by subtle tuning of the reaction conditions. Investigations of the mechanism suggest that the C-H activation proceeds via enamine formation.",

author = "Saunthwal, \{Rakesh K\} and Monika Patel and Sonu Kumar and Danodia, \{Abhinandan K.\} and Verma, \{Akhilesh K.\}",

year = "2015",

month = oct,

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doi = "10.1002/chem.201503657",

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journal = "Chemistry - A European Journal",

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T1 - Pd(II)‐Catalyzed C-H Activation of Styrylindoles:

T2 - Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

AU - Saunthwal, Rakesh K

AU - Patel, Monika

AU - Kumar, Sonu

AU - Danodia, Abhinandan K.

AU - Verma, Akhilesh K.

PY - 2015/10/6

Y1 - 2015/10/6

N2 - A novel PdII‐catalyzed approach for the direct synthesis of highly functionalized carbazoles from unprotected styrylindoles has been developed. The reaction features a variety of olefin substrates, which are readily switchable by subtle tuning of the reaction conditions. Investigations of the mechanism suggest that the C-H activation proceeds via enamine formation.

AB - A novel PdII‐catalyzed approach for the direct synthesis of highly functionalized carbazoles from unprotected styrylindoles has been developed. The reaction features a variety of olefin substrates, which are readily switchable by subtle tuning of the reaction conditions. Investigations of the mechanism suggest that the C-H activation proceeds via enamine formation.

U2 - 10.1002/chem.201503657

DO - 10.1002/chem.201503657

M3 - Article (Academic Journal)

C2 - 26437912

SN - 0947-6539

VL - 21

SP - 18601

EP - 18605

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 51

ER -

Pd(II)‐Catalyzed C-H Activation of Styrylindoles: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

Abstract

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