Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: An 'intramolecular embrace'

Katharine L. Bray; Craig P. Butts; Guy C. Lloyd-Jones; Martin Murray

doi:10.1039/a801170b

Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: An 'intramolecular embrace'

Katharine L. Bray
, Craig P. Butts
, Guy C. Lloyd-Jones^*
, Martin Murray

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

14 Citations (Scopus)

Abstract

The homochiral form of the complex [('P,N')₂Ni]²⁺ ('P,N' is a phosphino-heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a 'fitting' of the two 'P,N' ligands about the Ni that is reminiscent of an 'intramolecular embrace'.

Original language	English
Pages (from-to)	1421-1422
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/a801170b
Publication status	Published - 7 May 1998

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Organic & Biological

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title = "Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: An 'intramolecular embrace'",

abstract = "The homochiral form of the complex [('P,N')2Ni]2+ ('P,N' is a phosphino-heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a 'fitting' of the two 'P,N' ligands about the Ni that is reminiscent of an 'intramolecular embrace'.",

author = "Bray, \{Katharine L.\} and Butts, \{Craig P.\} and Lloyd-Jones, \{Guy C.\} and Martin Murray",

year = "1998",

month = may,

day = "7",

doi = "10.1039/a801170b",

language = "English",

pages = "1421--1422",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "9",

}

Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: An 'intramolecular embrace'. / Bray, Katharine L.; Butts, Craig P.; Lloyd-Jones, Guy C. et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 9, 07.05.1998, p. 1421-1422.

Research output: Contribution to journal › Article (Academic Journal) › peer-review

TY - JOUR

T1 - Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre

T2 - An 'intramolecular embrace'

AU - Bray, Katharine L.

AU - Butts, Craig P.

AU - Lloyd-Jones, Guy C.

AU - Murray, Martin

PY - 1998/5/7

Y1 - 1998/5/7

N2 - The homochiral form of the complex [('P,N')2Ni]2+ ('P,N' is a phosphino-heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a 'fitting' of the two 'P,N' ligands about the Ni that is reminiscent of an 'intramolecular embrace'.

AB - The homochiral form of the complex [('P,N')2Ni]2+ ('P,N' is a phosphino-heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a 'fitting' of the two 'P,N' ligands about the Ni that is reminiscent of an 'intramolecular embrace'.

UR - https://www.scopus.com/pages/publications/33748516767

U2 - 10.1039/a801170b

DO - 10.1039/a801170b

M3 - Article (Academic Journal)

AN - SCOPUS:33748516767

SN - 0300-9246

SP - 1421

EP - 1422

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 9

ER -

Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: An 'intramolecular embrace'

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