Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

KF Bowes; JM Cole; SLG Husheer; PR Raithby; TL Savarese; HA Sparkes; SJ Teat; JE Warren

doi:10.1039/b604039

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

KF Bowes
, JM Cole^*
, SLG Husheer
, PR Raithby
, TL Savarese
, HA Sparkes
, SJ Teat
, JE Warren

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article (Academic Journal) › peer-review

Abstract

The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Original language	English
Pages (from-to)	2448-2450
Number of pages	3
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b604039
Publication status	Published - 2006

Keywords

X-RAY-DIFFRACTION
METASTABLE LINKAGE ISOMERS
SULFUR-DIOXIDE COMPLEXES
EXCITED-STATES
TRANSITION
CRYSTALLOGRAPHY
EXCITATION
ION

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@article{a3c81332e29f4b28beb99f596b1dd190,

title = "Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)",

abstract = "The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36\% component of the structure within a single crystal upon irradiation using a tungsten lamp.",

keywords = "X-RAY-DIFFRACTION, METASTABLE LINKAGE ISOMERS, SULFUR-DIOXIDE COMPLEXES, EXCITED-STATES, TRANSITION, CRYSTALLOGRAPHY, EXCITATION, ION",

author = "KF Bowes and JM Cole and SLG Husheer and PR Raithby and TL Savarese and HA Sparkes and SJ Teat and JE Warren",

year = "2006",

doi = "10.1039/b604039",

language = "English",

pages = "2448--2450",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

AU - Bowes, KF

AU - Cole, JM

AU - Husheer, SLG

AU - Raithby, PR

AU - Savarese, TL

AU - Sparkes, HA

AU - Teat, SJ

AU - Warren, JE

PY - 2006

Y1 - 2006

N2 - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

AB - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

KW - X-RAY-DIFFRACTION

KW - METASTABLE LINKAGE ISOMERS

KW - SULFUR-DIOXIDE COMPLEXES

KW - EXCITED-STATES

KW - TRANSITION

KW - CRYSTALLOGRAPHY

KW - EXCITATION

KW - ION

U2 - 10.1039/b604039

DO - 10.1039/b604039

M3 - Article (Academic Journal)

SN - 1359-7345

SP - 2448

EP - 2450

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

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