Projects per year
Abstract
A photochemical method for converting aliphatic alcohols into boronic esters is described. Preactivation of the alcohol as a 2‐iodophenyl‐thionocarbonate enables a novel Barton‐McCombie‐type radical deoxygenation that proceeds efficiently with visible light irradiation and without the requirement for a photocatalyst, a radical initiator, or tin or silicon hydrides. The resultant alkyl radical is intercepted by bis(catecholato)diboron, furnishing boronic esters from a diverse range of structurally complex alcohols.
Original language | English |
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Number of pages | 6 |
Journal | Angewandte Chemie - International Edition |
Early online date | 15 Oct 2019 |
DOIs | |
Publication status | E-pub ahead of print - 15 Oct 2019 |
Keywords
- Boronsäureester
- Borylierungen
- Desoxygenierung
- Photochemie
- Radikalreaktionen
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Dive into the research topics of 'Photoinduced Deoxygenative Borylations of Aliphatic Alcohols'. Together they form a unique fingerprint.Projects
- 1 Finished
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FRESCO: Efficient, Flexible Synthesis of Molecules with Tailored Shapes: from Photoswitchable Helices to anti-Cancer Compounds
Aggarwal, V. K. (Principal Investigator)
1/10/15 → 31/03/21
Project: Research