Skip to content

Photoinduced Deoxygenative Borylations of Aliphatic Alcohols

Research output: Contribution to journalArticle

Original languageEnglish
Number of pages6
JournalAngewandte Chemie - International Edition
Early online date15 Oct 2019
DOIs
DateAccepted/In press - 15 Oct 2019
DateE-pub ahead of print (current) - 15 Oct 2019

Abstract

A photochemical method for converting aliphatic alcohols into boronic esters is described. Preactivation of the alcohol as a 2‐iodophenyl‐thionocarbonate enables a novel Barton‐McCombie‐type radical deoxygenation that proceeds efficiently with visible light irradiation and without the requirement for a photocatalyst, a radical initiator, or tin or silicon hydrides. The resultant alkyl radical is intercepted by bis(catecholato)diboron, furnishing boronic esters from a diverse range of structurally complex alcohols.

    Research areas

  • Boronsäureester, Borylierungen, Desoxygenierung, Photochemie, Radikalreaktionen

Documents

Documents

  • Full-text PDF (accepted author manuscript)

    Rights statement: This is the author accepted manuscript (AAM). The final published version (version of record) is available online via Wiley at https://onlinelibrary.wiley.com/doi/10.1002/ange.201910051. Please refer to any applicable terms of use of the publisher.

    Accepted author manuscript, 1 MB, PDF document

    Embargo ends: 15/10/20

    Request copy

DOI

View research connections

Related faculties, schools or groups