Photomodulable phosphines incorporating diarylethene moieties

Giulio Bianchini; Giorgio Strukul; Duncan F. Wass; Alessandro Scarso

doi:10.1039/c4ra16127k

Photomodulable phosphines incorporating diarylethene moieties

Giulio Bianchini, Giorgio Strukul, Duncan F. Wass^*, Alessandro Scarso

^*Corresponding author for this work

Research output: Contribution to journal › Article (Academic Journal) › peer-review

13 Citations (Scopus)

Abstract

Incorporation of the dithienylethene moiety as a substituent provides new 'switchable' phosphine ligands whose electronic properties are reversibly modulated by light. The presence of electron-withdrawing substituents in the photochromic unit increases the σ-donation gap between the photo-modulated open and closed phosphine isomers.

Original language	English
Pages (from-to)	10795-10798
Number of pages	4
Journal	RSC Advances
Volume	5
Issue number	14
DOIs	https://doi.org/10.1039/c4ra16127k
Publication status	Published - 2015

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10.1039/c4ra16127k

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title = "Photomodulable phosphines incorporating diarylethene moieties",

abstract = "Incorporation of the dithienylethene moiety as a substituent provides new 'switchable' phosphine ligands whose electronic properties are reversibly modulated by light. The presence of electron-withdrawing substituents in the photochromic unit increases the σ-donation gap between the photo-modulated open and closed phosphine isomers.",

author = "Giulio Bianchini and Giorgio Strukul and Wass, {Duncan F.} and Alessandro Scarso",

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T1 - Photomodulable phosphines incorporating diarylethene moieties

AU - Bianchini, Giulio

AU - Strukul, Giorgio

AU - Wass, Duncan F.

AU - Scarso, Alessandro

PY - 2015

Y1 - 2015

N2 - Incorporation of the dithienylethene moiety as a substituent provides new 'switchable' phosphine ligands whose electronic properties are reversibly modulated by light. The presence of electron-withdrawing substituents in the photochromic unit increases the σ-donation gap between the photo-modulated open and closed phosphine isomers.

AB - Incorporation of the dithienylethene moiety as a substituent provides new 'switchable' phosphine ligands whose electronic properties are reversibly modulated by light. The presence of electron-withdrawing substituents in the photochromic unit increases the σ-donation gap between the photo-modulated open and closed phosphine isomers.

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U2 - 10.1039/c4ra16127k

DO - 10.1039/c4ra16127k

M3 - Article (Academic Journal)

AN - SCOPUS:84921677515

VL - 5

SP - 10795

EP - 10798

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 14

ER -

Photomodulable phosphines incorporating diarylethene moieties

Abstract

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